2-金刚烷醇
2-金刚烷醇结构式
|
常用名 | 2-金刚烷醇 | 英文名 | 2-Adamantanol |
|---|---|---|---|---|
| CAS号 | 700-57-2 | 分子量 | 152.23 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 255.2±8.0 °C at 760 mmHg | |
| 分子式 | C10H16O | 熔点 | 258-262 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 105.5±10.9 °C |
|
Low-temperature X-ray structural studies of the ester and ether derivatives of cis- and trans-4-tert-butyl cyclohexanol and 2-adamantanol: application of the variable oxygen probe to determine the relative sigma-donor ability of C-H and C-C bonds.
Org. Biomol. Chem. 1(17) , 3094-101, (2003) Results of low-temperature X-ray structural studies for five cis-, and three trans-4-tert-butyl cyclohexanol, and six 2-adamantanol ester and ether derivatives are reported. Plots of C-OR bond distance against pKa(ROH) for derivatives of axial alcohol (5), eq... |
|
|
Synthesis and antimicrobial activity of new adamantane derivatives III.
Il Farmaco 57(8) , 619-24, (2002) Some novel ester imides synthesised from trimellitic acid anhydride and 1-adamantanol or 2-adamantanol, were tested as antimicrobial compounds. Unfortunately, these agents showed a modest antibacterial activity (MIC > 6 microg/ml). However, a comparison of th... |
|
|
Regioselective hydroxylation of adamantane by Streptomyces griseoplanus cells.
Appl. Microbiol. Biotechnol. 71(4) , 502-4, (2006) Hydroxylation of adamantane using whole cells of bacteria, actinomyces, and molds was examined. The structure of the product was determined using gas chromatography (GC), nuclear magnetic resonance (NMR), and mass spectroscopy (MS). Among 470 strains tested, ... |
|
|
Photoaffinity labeling of cytochrome P450 2B4: capture of active site heme ligands by a photocarbene.
Biochemistry 33(3) , 807-17, (1994) Spiro[adamantane-2,2'-diazirine], which produces adamantyl carbene upon photolysis, binds tightly to P450 2B4 (KS = 3.2 microM), giving a normal substrate binding difference spectrum. Irradiation of 2-[3H]adamantane diazirine at 365 nm in the presence of nati... |
|
|
Thermal properties of adamantanol derivatives and their beta-cyclodextrin complexes in phosphatidylcholine bilayers.
Life Sci. 62(20) , 1901-10, (1998) Differential Scanning Calorimetry (DSC) has been applied to study the thermal properties of the membrane perturbing antibacterial octyl- and dodecyl-bromide salts of quaternary dimethylamino adamantanol (ADM-8 and ADM-12 correspondingly) incorporated in free ... |