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2-碘苄醇

2-碘苄醇结构式
2-碘苄醇结构式
品牌特惠专场
常用名 2-碘苄醇 英文名 (2-Iodophenyl)methanol
CAS号 5159-41-1 分子量 234.03
密度 1.9±0.1 g/cm3 沸点 288.3±15.0 °C at 760 mmHg
分子式 C7H7IO 熔点 89-92 °C(lit.)
MSDS 中文版 美版 闪点 128.2±20.4 °C

Synthesis of seven-membered lactones via nickel- and zinc-catalyzed highly regio- and stereoselective cyclization of 2-iodobenzyl alcohols with propiolates.

J. Am. Chem. Soc. 124(20) , 5630-1, (2002)

A new class of substituted seven-membered lactones 3 were conveniently synthesized via cyclization of o-iodobenzyl alcohol 1 (o-IC(6)H(4)CH(2)OH) with various propiolates 2 (RC triple bond CCOOMe) in the presence of Ni(dppe)Br(2) and Zn powder in acetonitrile...

Synthesis of indenones via palladium-catalyzed annulation of internal alkynes. Larock RC, et al.

J. Org. Chem. 58(17) , 4579-83, (1993)