![]() 2-碘苄醇结构式
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常用名 | 2-碘苄醇 | 英文名 | (2-Iodophenyl)methanol |
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CAS号 | 5159-41-1 | 分子量 | 234.03 | |
密度 | 1.9±0.1 g/cm3 | 沸点 | 288.3±15.0 °C at 760 mmHg | |
分子式 | C7H7IO | 熔点 | 89-92 °C(lit.) | |
MSDS | 中文版 美版 | 闪点 | 128.2±20.4 °C |
Synthesis of seven-membered lactones via nickel- and zinc-catalyzed highly regio- and stereoselective cyclization of 2-iodobenzyl alcohols with propiolates.
J. Am. Chem. Soc. 124(20) , 5630-1, (2002) A new class of substituted seven-membered lactones 3 were conveniently synthesized via cyclization of o-iodobenzyl alcohol 1 (o-IC(6)H(4)CH(2)OH) with various propiolates 2 (RC triple bond CCOOMe) in the presence of Ni(dppe)Br(2) and Zn powder in acetonitrile... |
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Synthesis of indenones via palladium-catalyzed annulation of internal alkynes. Larock RC, et al.
J. Org. Chem. 58(17) , 4579-83, (1993)
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