亚硫酸氢钠穿心莲内酯
亚硫酸氢钠穿心莲内酯结构式
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常用名 | 亚硫酸氢钠穿心莲内酯 | 英文名 | Tricyclo[3.3.1.13,7]decane,1-iodo- |
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| CAS号 | 768-93-4 | 分子量 | 262.13100 | |
| 密度 | 1.63 g/cm3 | 沸点 | 265.7ºC at 760 mmHg | |
| 分子式 | C10H15I | 熔点 | 75-76ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 115.9ºC |
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Electrosynthetic reduction of 1-iodoadamantane forming 1,1'-biadamantane and adamantane in aprotic solvents: insonation switches the mechanism from dimerisation to exclusive monomer formation.
Ultrason. Sonochem. 14(5) , 502-8, (2007) The combination of ultrasound and electrochemistry -sonoelectrochemistry can produce a variety of effects within an electrochemical system including enhanced mass transport, in situ cleaning of an electrode surface, diminution of the diffusion layer, and poss... |
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Fluorescent quenching of the 2-naphthoxide anion by aliphatic and aromatic halides. Mechanism and consequences of electron transfer reactions.
J. Org. Chem. 68(6) , 2362-8, (2003) The fluorescent excited state of the 2-naphthoxide ion (1) is quenched by aliphatic and aromatic halides according to an electron-transfer mechanism, with generation of the corresponding alkyl and aryl radicals by a concerted or consecutive C-X bond fragmenta... |
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[1-(1-Adamantylamino)ethyl-idene]oxonium methane-sulfonate.
Acta Crystallogr. Sect. E Struct. Rep. Online 65(Pt 6) , o1307, (2009) In the title salt, C(12)H(20)NO(+)·CH(3)SO(3) (-), the [1-(1-adamantyl-amino)ethyl-idene]oxonium cations and methane-sulfonate anions are linked into chains along the a axis via O-H⋯O and N-H⋯O hydrogen bonds. All non-H atoms of the acetamido group are essent... |
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Regiochemistry of the photostimulated reaction of the phthalimide anion with 1-iodoadamantane and tert-butylmercury chloride by the S(RN)1 mechanism.
J. Org. Chem. 67(3) , 1012-5, (2002) The photostimulated reaction of the phthalimide anion (1) with 1-iodoadamantane (2) gave 3-(1-adamantyl) phthalimide (3) (12%) and 4-(1-adamantyl) phthalimide (4) (45%), together with the reduction product adamantane (AdH) (21%). The lack of reaction in the d... |
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J. Am. Chem. Soc. 115 , 1187, (1993)
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Synlett , 143, (1993)
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Photostimulated reaction of 1-iodoadamantane with carbanionic nucleophiles in DMSO by the SRN1 mechanism. Borosky GL, et al.
J. Org. Chem. 55(12) , 3705-3707, (1990)
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Dimerization of Cubene. 1-Iodoadamantane as a Probe for Radical Intermediates. Lukin K and Eaton PE.
J. Am. Chem. Soc. 117(29) , 7652-7656., (1995)
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Rate study of haloadamantane reduction by samarium diiodide. Lin T-Y, et al.
J. Chin. Chem. Soc. 49(6) , 969-973. , (2002)
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