双[(α,α,α',α'-四甲基-1,3-苯二丙酸)铑]
![双[(α,α,α',α'-四甲基-1,3-苯二丙酸)铑]结构式](https://image.chemsrc.com/caspic/266/819050-89-0.png)
双[(α,α,α',α'-四甲基-1,3-苯二丙酸)铑]结构式
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常用名 | 双[(α,α,α',α'-四甲基-1,3-苯二丙酸)铑] | 英文名 | Bis[rhodium(a,a,a#,a#-tetramethyl-1,3-benzenedipropionic acid)] |
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| CAS号 | 819050-89-0 | 分子量 | 762.49800 | |
| 密度 | N/A | 沸点 | 437ºC at 760 mmHg | |
| 分子式 | C32H44O8Rh2 | 熔点 | >300ºC | |
| MSDS | 中文版 美版 | 闪点 | 232.2ºC |
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Catalytic intermolecular amination of C-H bonds: method development and mechanistic insights.
J. Am. Chem. Soc. 129 , 562, (2007) Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstituted amines through stereospecific insertion into enantiome... |
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