苯基乙烯基亚砜
苯基乙烯基亚砜结构式
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常用名 | 苯基乙烯基亚砜 | 英文名 | (Vinylsulfinyl)benzene |
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| CAS号 | 20451-53-0 | 分子量 | 152.214 | |
| 密度 | 1.2±0.1 g/cm3 | 沸点 | 317.1±11.0 °C at 760 mmHg | |
| 分子式 | C8H8OS | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 145.6±19.3 °C |
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Reactions of Vinyl Sulfoxides with Magnesium Amides. One-Pot Synthesis of Symmetrical and Unsymmetrical beta-(Dialkylamino) Dithioacetals.
J. Org. Chem. 62(23) , 8015-8017, (1997) Vinyl sulfoxides (PhSOCR(1)=CHR(2): R(1) = H, Me, or Ph; R(2) = H or Me) were treated with (dialkylamino)magnesium reagents, generated in situ from the reaction of EtMgBr with secondary amines (R(3)R(4)NH: R(3) = Et, i-Pr, or Bn; R(4) = Me, Et, or i-Pr) in re... |
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The formation of bicyclo[n.2.0]alkan-1-ols from the reaction of the lithium enolates of simple ketones and phenyl vinyl sulfoxide.
Org. Biomol. Chem. 1(8) , 1347-53, (2003) The enolates generated from cyclopentanone, cycloheptanone or cyclooctanone and LDA at -78 degrees C in THF react with (+/-)-phenyl vinyl sulfoxide under controlled conditions of temperature, reaction time, and concentration. Upon oxidation with MCPBA of the ... |
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The structures of different diastereomers of bicyclo[2.2.1]hept-5-en-2-yl phenyl sulfoxide.
Acta Crystallogr. B 45 ( Pt 1) , 93-9, (1989) Three diastereomers of bicyclo[2.2.1]hept-5-en-2-yl phenyl sulfoxide were prepared by Diels-Alder [4 + 2] cycloadditions between phenyl vinyl sulfoxide and cyclopentadiene. The isomers were separated by column chromatography on silica gel and repeated recryst... |
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Use of phenyl vinyl sulfoxide as an acetylene equivalent in Diels-Alder cycloadditions. Paquette LA, et al.
J. Am. Chem. Soc. 100(5) , 1597-99, (1978)
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