2-(叔丁基二甲基甲硅烷基)-1,3-二噻烷
2-(叔丁基二甲基甲硅烷基)-1,3-二噻烷结构式
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常用名 | 2-(叔丁基二甲基甲硅烷基)-1,3-二噻烷 | 英文名 | 2-(TERT-BUTYLDIMETHYLSILYL)-1,3-DITHIANE |
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| CAS号 | 95452-06-5 | 分子量 | 234.49700 | |
| 密度 | 1.01 g/mL at 25ºC(lit.) | 沸点 | 124ºC5 mm Hg(lit.) | |
| 分子式 | C10H22S2Si | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 221 °F |
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Multicomponent linchpin couplings of silyl dithianes: synthesis of the Schreiber C(16-28) trisacetonide subtarget for mycoticins A and B.
Org. Lett. 1(12) , 2001-4, (1999) [formula: see text] An efficient synthesis of trisacetonide (+)-11, the Schreiber C(16-28) subtarget for mycoticins A and B, is described. The key synthetic transformation entails a one-flask, five-component linchpin coupling tactic. |
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A general, convergent strategy for the construction of indolizidine alkaloids: total syntheses of (-)-indolizidine 223AB and alkaloid (-)-205B.
J. Org. Chem. 71 , 2547, (2006) N-Toluenesulfonyl aziridines comprise effective second electrophiles in the solvent controlled three-component linchpin union of silyl dithianes for the stereocontrolled convergent elaboration of protected 1,5-amino alcohols. This tactic, in conjunction with ... |
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Total synthesis of the neotropical poison-frog alkaloid (-)-205B.
Org. Lett. 7 , 3247, (2005) [reaction: see text]. A stereocontrolled total synthesis of the neotropical poison-frog alkaloid (-)-205B (1) has been achieved, employing a dithiane three-component linchpin coupling, a one-pot sequential construction of the embedded indolizidine ring, and r... |