1,1'-双(二苯基膦)二茂铁
1,1'-双(二苯基膦)二茂铁结构式
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常用名 | 1,1'-双(二苯基膦)二茂铁 | 英文名 | 1,1-Bis(diphenylphosphino)ferrocene |
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| CAS号 | 12150-46-8 | 分子量 | 558.410 | |
| 密度 | N/A | 沸点 | 363.8ºC at 760mmHg | |
| 分子式 | C34H28FeP2 | 熔点 | 181-182 °C (dec.)(lit.) | |
| MSDS | 美版 | 闪点 | 182.8ºC |
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Catalytic selective deuteration of halo(hetero)arenes.
Org. Biomol. Chem. 14 , 3091-7, (2016) Deuterium labeled aromatic and heteroaromatic compounds are synthesized in good to excellent yields with >98% deuterium purity via palladium catalyzed deuterodehalogenation reaction using commercially available and inexpensive reagents. Selective deuteration ... |
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A new one-Pot synthesis of alkynylphosphonates
Org. Lett. 2 , 3873, (2000) A method for the palladium-catalyzed synthesis of alkynylphosphonates from 1,1-dibromo-1-alkenes has been developed. In general, the best catalyst system for this transformation was found to be Pd(OAc)(2), dppf, H-phosphonate, propylene oxide, DMF, 80 degrees... |
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Stereoselective ring opening of meso bicyclic hydrazines: a straightforward approach to hydrazino cyclopentenic cores.
Org. Lett. 5 , 4771, (2003) The diastereoselective synthesis of hydrazinocyclopentenes 6 or 7 can be achieved in a straightforward manner from Diels-Alder adduct 4 using an acid-catalyzed rearrangement or a palladium-catalyzed allylic substitution reaction. In the latter case, enantioen... |
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Zirconium ion selective electrode based on bis(diphenylphosphino) ferrocene incorporated in a poly(vinyl chloride) matrix.
Anal. Chim. Acta 584(2) , 302-307, (2007) A novel potentiometric zirconium--PVC matrix membrane sensor incorporating bis(diphenylphosphino) ferrocene as an electroactive material and tris(2-ethylhexyl)phosphate as solvent mediator is described. In mixed acetate buffer solution of pH 4.8, the sensor d... |
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Tetrahedron 62 , 9002, (2006)
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Tanimori, Shinji; et al.
Synthesis 5 , 865-869, (2006)
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Palucki, M.;Wolfe, J. P.; Buchwald, S.-L.
J. Am. Chem. Soc. 118 , 10333, (1996)
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Driver, M. S.; Hartwig, J. F.
J. Am. Chem. Soc. 118 , 7217, (1996)
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Wolfe, J. P.; Buchwald, S. L.
J. Am. Chem. Soc. 119 , 6054, (1997)
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Anastasia, L.; Dumond, Y. R.; Negishi, E.
European J. Org. Chem. , 3039, (2001)
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