Addition of Organocerium Reagents to Morpholine Amides: Synthesis of Important Pheromone Components of Achaea j anata

M Badioli, R Ballini, M Bartolacci, G Bosica…

文献索引：Badioli, Michele; Ballini, Roberto; Bartolacci, Massimo; Bosica, Giovanna; Torregiani, Elisabetta; Marcantoni, Enrico The Journal of organic chemistry, 2002 , vol. 67, # 25 p. 8938 - 8942

全文：HTML全文

被引用次数: 47

摘要

Readily preparable morpholine amides hitch in good yields with organocerium reagents to produce ketones. Even in the presence of substrates and reagents with high steric hindrance, the organometallic compounds prepared from dry cerium (III) chloride and organomagnesium or organolithium compounds at-78° C add cleanly to morpholine amides. The low cost of starting materials makes this new scheme of synthesis very interesting for ...