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869-24-9生产厂家

869-24-9价格

相关CAS号：
869-24-9 4584-46-7
1942-52-5 1606-01-5
870-24-6 1833967-65-9
19774-82-4 5987-82-6
37408-85-8 1069-72-3

869-24-9

869-24-9结构式
869-24-9结构式

化源商城直购

中文名 2-二乙氨基氯乙烷盐酸盐
英文名 2-Diethylaminoethylchloride Hydrochloride
中文别名 盐酸-2-二乙氨基氯乙烷
英文别名 (β-Chloroethyl)diethylamine hydrochloride
β-(Diethylamino)ethyl chloride hydrochloride
Diethyl(β-chloroethyl)amine hydrochloride
2-Diethylamino ethylchloride HCL
2-Chloro-N,N-diethylethanamine hydrochloride (1:1)
MFCD00008385
β-Chloroethyldiethylamine hydrochloride
2-Diethylaminoethylchloride hydrochloride
Diethyl-β-chloroethylamine hydrochloride
Ethanamine, 2-chloro-N,N-diethyl-, hydrochloride (1:1)
N,N-Diethyl-β-chloroethylamine hydrochloride
EINECS 210-673-4
Amiodarone Impurity 8
沸点 255 °C(lit.)
熔点 50-53 °C(lit.)
分子式 C6H15Cl2N
分子量 172.096
闪点 186 °F
精确质量 171.058151
PSA 3.24000
LogP 2.36900
外观性状 透明至米色晶体
储存条件

保持容器密封，储存在阴凉，干燥的地方。

稳定性

常温常压下稳定，避免氧化物 碱接触

有毒物质，与皮肤接触、吞咽有害。吸入极毒，刺激眼睛，刺激呼吸道，刺激皮肤。万一接触眼睛，立即使用大量清水冲洗并送医诊治。出现意外或者感到不适，立即就医（最好带去产品容器标签）。
水溶解性 2000 g/L (20 ºC)
计算化学

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:1

3.氢键受体数量:1

4.可旋转化学键数量:4

5.互变异构体数量:无

6.拓扑分子极性表面积3.2

7.重原子数量:9

8.表面电荷:0

9.复杂度:43.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2
更多

1. 性状：白色针状结晶

2. 密度（g/mL,25/4℃）：未确定

3. 相对蒸汽密度（g/mL,空气=1）：未确定

4. 熔点（ºC）：210-212

5. 沸点（ºC,常压）：255

6. 沸点（ºC,5.2kPa）：未确定

7. 折射率：未确定

8. 闪点（ºF）：186

9. 比旋光度（º）：未确定

10. 自燃点或引燃温度（ºC）：未确定

11. 蒸气压（kPa,25ºC）：未确定

12. 饱和蒸气压（kPa,60ºC）：未确定

13. 燃烧热（KJ/mol）：未确定

14. 临界温度（ºC）：未确定

15. 临界压力（KPa）：未确定

16. 油水（辛醇/水）分配系数的对数值：未确定

17. 爆炸上限（%,V/V）：未确定

18. 爆炸下限（%,V/V）：未确定

19. 溶解性：溶于乙醇，微溶于丙酮。
Name: 2-Diethylaminoethyl Chloride Hydrochloride 99.5% Material Safety Data Sheet
Synonym: 2-Chloro-N,N-Diethylethylamine Hydrochloride; 2-Chlorotriethylamine Hydrochloride; DE
CAS: 869-24-9
Section 1 - Chemical Product MSDS Name:2-Diethylaminoethyl Chloride Hydrochloride 99.5% Material Safety Data Sheet
Synonym:2-Chloro-N,N-Diethylethylamine Hydrochloride; 2-Chlorotriethylamine Hydrochloride; DE
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
869-24-9 2-Diethylaminoethylchloride Hydrochlor 99.5 212-786-4
Hazard Symbols: T+
Risk Phrases: 26 36/37/38 24/25
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Very toxic by inhalation. Irritating to eyes, respiratory system and skin. Toxic in contact with skin and if swallowed.Hygroscopic (absorbs moisture from the air).The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be fatal if absorbed through the skin.
May cause dermatitis.
Ingestion:
May be fatal if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. May cause burning sensations, coughing, wheezing, laryngitis, shortness of breath and headache.
Inhalation:
May be fatal if inhaled. Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May cause dyspnea (difficult or labored breathing). May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
Laboratory experiments have resulted in mutagenic effects.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Use only in a chemical fume hood. Wash clothing before reuse. Keep from contact with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Poison room locked. Store protected from moisture.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 869-24-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: white to beige
Odor: characteristic odor
pH: 5 (100g/l aq. sol.)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 208.00 - 212.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 220 deg C
Solubility in water: 2000 g/l (20 c)
Specific Gravity/Density:
Molecular Formula: C6H14ClN.HCl
Molecular Weight: 172.10
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions. Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid:
Dust generation, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 869-24-9: YE1050000 LD50/LC50:
CAS# 869-24-9: Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, skin: 500 mg Severe; Inhalation, rat: LC50 = 103 mg/m3/4H; Oral, rat: LD50 = 50 mg/kg; Skin, rabbit: LD50 = 125 mg/kg.
LC50 1Hr (dust) = .412mg/L or 58.53ppm Carcinogenicity:
2-Diethylaminoethylchloride Hydrochloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: I
IMO
Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: I
RID/ADR
Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: I
Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 24/25 Toxic in contact with skin and if swallowed.
R 26 Very toxic by inhalation.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 869-24-9: 2
Canada
CAS# 869-24-9 is listed on Canada's DSL List.
CAS# 869-24-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 869-24-9 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

1、急性毒性：小鼠口经LD50：320mg/kg；大鼠口经LD50：50mg/kg

2、急性毒性：小鼠腹腔LD50：71mg/kg；大鼠腹腔LD50：30mg/kg

生态学数据:

对水是危害的，即使是小量的产品渗入地下也会对饮用水造成危险若无政府许可，勿将材料排入周围环境。

CHEMICAL IDENTIFICATION

RTECS NUMBER :
YE1050000
CHEMICAL NAME :
Triethylamine, 2-chloro-, hydrochloride
CAS REGISTRY NUMBER :
869-24-9
LAST UPDATED :
199712
DATA ITEMS CITED :
21
MOLECULAR FORMULA :
C6-H14-Cl-N.Cl-H
MOLECULAR WEIGHT :
172.12
WISWESSER LINE NOTATION :
G2N2&2 &GH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
50 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
103 mg/m3/4H
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - tremor Lungs, Thorax, or Respiration - dyspnea
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
30 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
320 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
71 mg/kg
TOXIC EFFECTS :
Behavioral - ataxia
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
125 mg/kg
TOXIC EFFECTS :
Gastrointestinal - other changes Skin and Appendages - dermatitis, other (after systemic exposure)
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
40 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - wild bird species
DOSE/DURATION :
42 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Mutation in mammalian somatic cells
TEST SYSTEM :
Rodent - mouse Lymphocyte
DOSE/DURATION :
22 umol/L
REFERENCE :
ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 3,33,1981 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7462 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 4354 (estimated) No. of Female Employees: 729 (estimated)

符号 GHS05 GHS06
GHS05, GHS06
信号词 Danger
危害声明 H300 + H310 + H330-H315-H318-H335
警示性声明 Missing Phrase - N15.00950417-P280-P302 + P352 + P310-P304 + P340 + P310-P305 + P351 + P338 + P310
个人防护装备 Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P2 (EN 143) respirator cartridges;type P3 (EN 143) respirator cartridges
危害码 (欧洲) Xn, T, Xi, T+
风险声明 (欧洲) R24/25;R26;R36/37/38
安全声明 (欧洲) S26-S36-S45-S36/37/39-S28A
危险品运输编码 UN 2811 6.1/PG 2
WGK德国 3
RTECS号 DC2810000
包装等级 II
危险类别 6.1
海关编码 29211980
109-89-7结构式

109-89-7
107-07-3结构式

107-07-3

~46%

869-24-9结构式

869-24-9
文献：CHINA PHARMACEUTICAL UNIVERSITY; Xiang, Hua; Wang, Tianlin; Xiao, Hong; You, Qidong; Yao, Yao; Li, Xiaobo; Liao, Qingjiang Patent: US2013/85140 A1, 2013 ; Location in patent: Paragraph 0060; 0061 ;
100-37-8结构式

100-37-8

~%

869-24-9结构式

869-24-9
文献：Journal of the Chemical Society, , p. 2443
107-06-2结构式

107-06-2
109-89-7结构式

109-89-7

~46%

869-24-9结构式

869-24-9
文献：Li, Xuyuan; Meng, Yanfa; Zhao, Kehao; Tu, Weixia ACH - Models in Chemistry, 1997 , vol. 134, # 4 p. 383 - 393
5449-19-4结构式

5449-19-4

~%

869-24-9结构式

869-24-9
文献：International Journal of Chemical Kinetics, , vol. 26, # 2 p. 309 - 315

由N,N’-二乙氨基乙醇与氯化亚砜反应而得。

海关编码 29211980

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