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| 中文名 | 2,6-二异丙基苯基亚氨基叔丁基亚苯基钼(Ⅵ)双(叔丁醇化物) |
|---|---|
| 英文名 | butan-1-ol,[2,6-di(propan-2-yl)phenyl]imino-(2-methyl-2-phenylpropylidene)molybdenum |
| 中文别名 | 2,6-二异丙基亚胺双叔丁氧基钼 |
| 英文别名 |
2,5-DIHYDROTHIOPHENE-3-CARBOXYLIC ACID METHYL ESTER
2,6-Diisopropylphenylimidoneophylidene molybdenum(VI) bis(t-butoxide) |
| 密度 | 1 g/cm3 |
|---|---|
| 分子式 | C30H47MoNO2 |
| 分子量 | 549.66000 |
| 精确质量 | 551.26600 |
| PSA | 30.82000 |
| LogP | 9.14830 |
| 分子结构 | 1、摩尔折射率：无可用的 2、摩尔体积（cm3/mol）：无可用的 3、等张比容（90.2K）：无可用的 4、表面张力（dyne/cm）：无可用的 5、介电常数：无可用的 6、极化率（10-24cm3）：无可用的 7、单一同位素质量：551.266087 Da 8、标称质量：551 Da 9、平均质量：549.6397 Da |
| 更多 | 1. 性状：未确定 2. 密度（g/mL,20℃）：1.0 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,KPa）：未确定 7. 折射率：未确定 8. 闪点（ºC）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（Pa,20ºC）：未确定 12. 饱和蒸气压（KPa,20ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
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Section 1: Product Identification Chemical Name:2,6-Diisopropylphenylimido neophylidene molybdenum(VI) bis(t-butoxide) CAS Registry Number:126949-65-3 Formula:Mo(C10H12)(C12H17N)(OC4H9)2 EINECS Number:none Chemical Family:organometallic complexes Synonym:Schrock Hoveyda catalyst
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound126949-65-3100%10mg/m3( as Mo)15mg/m3 (as Mo) Section 3: Hazards Identification Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:Causes severe irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to skin, eyes and respiratory tract. Ingestion:No specific information is available on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. No information available on long-term chronic effects. t-butanol in high doses has acted as a reproductive Chronic Health Affects: effector. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in Inhalation: breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry powder or foam. If involved in a fire, fire fighters should be equipped with NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Handling and Storage:Handle and store the material under an inert atmosphere of nitrogen or argon. Keep away from heat. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow to orange powder Molecular Weight:549.65 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:1 Odor:not determined Solubility in Water:reacts with water SECTION 10: Stability and Reactivity Stability:air and moisture sensitive (store cold) Hazardous Polymerization:No hazardous polymerization. Conditions to Avoid:contact with air and moisture Incompatibility:oxidizing agents and halogens Decomposition Products:carbon monoxide, carbon dioxide, organic fumes and molybdenum oxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
| 风险声明 (欧洲) | 20/21/22-36/37/38 |
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| 安全声明 (欧洲) | 22-36/37/39 |