3084-50-2

• 常用中文名：三丁基膦硫化物
• 常用英文名：TRIBUTYLPHOSPHINE SULFIDE
• CAS号：3084-50-2
• 分子式：C₁₂H₂₇PS
• 分子量：234.38200
• 发布时间：2016-03-09 18:39:40
• 更新时间：2026-07-01 16:05:49

名称

• 中文名: 三丁基膦硫化物
• 英文名: tributyl(sulfanylidene)-λ5-phosphane
• 中文别名: 三丁基硫化膦; 1,3-二甲基-1,1,3,3-四(2-苯基乙氧基)二硅氧烷; 三正丁基硫膦
• 英文别名: Tributylphosphine sulfide; Einecs -7; Tributylphosphine sulfide min. , ( S, dissolved in TBP); tributylphosphine sulphide; Phosphine sulfide,tributyl; Tributylfosfinsulfid; Tri-n-butylphosphine sulfide; Tributylfosfinsulfid [czech]; Tri-n-butylphosphinsulfid; HISHICOLIN PS-4; Phosphine, tributyl-, sulfide; Tributylphosphine sulfide/tributylphosphine (50:50 mixture), CYTOP; Tributylphosphine sulfide min; EINECS 221-393-7; Phosphine,tributyl-,sulfide; Tributylphosphine sulphide; Ai3-51152; Phosphine sulfide, tributyl; tributylphosphane sulfide; thio tri n-butylphosphine; Brn

物化性质

• 密度: 0.906g/cm3
• 沸点: 302.1ºC at 760mmHg
• 分子式: C₁₂H₂₇PS
• 分子量: 234.38200
• 闪点: 136.5ºC
• 精确质量: 234.15700
• PSA: 41.90000
• LogP: 5.51680
• 折射率: 1.467

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : SZ2800000 CHEMICAL NAME : Phosphine sulfide, tributyl- CAS REGISTRY NUMBER : 3084-50-2 BEILSTEIN REFERENCE NO. : 1762257 LAST UPDATED : 199612 DATA ITEMS CITED : 5 MOLECULAR FORMULA : C12-H27-P-S MOLECULAR WEIGHT : 234.42 WISWESSER LINE NOTATION : SP4&4&4 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Open irritation test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962 TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1119,1986 TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration into the eye SPECIES OBSERVED : Rodent - rabbit REFERENCE : 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1119,1986 ** ACUTE TOXICITY DATA ** TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 930 uL/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 1 mL/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962

安全

• 风险声明 (欧洲): 36/38
• WGK德国: 3
• 海关编码: 2930909090

合成路线

110-06-5 998-40-3 ~82% 3084-50-2

文献：Ohmori, Hidenobu; Maeda, Hatsuo; Konomoto, Kohichi; Sakai, Kiyoshi; Masui, Masaichiro Chemical and Pharmaceutical Bulletin, 1987 , vol. 35, # 11 p. 4473 - 4481

10544-50-0 15076-72-9 ~10% 121872-72-8 3084-50-2

文献：O'Mahoney, Caroline A.; Parkin, Ivan P.; Williams, David J.; Woollins, J. Derek Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1989 , p. 1179 - 1186

998-40-3 ~% 3084-50-2

文献：Demarcq, Michel C. Phosphorus, Sulfur and Silicon and Related Elements, 1998 , vol. 134-135, p. 307 - 320

109-79-5 67-68-5 ~0% 75-18-3 628-29-5 详细

文献：Trofimov; Gusarova; Verkhoturova; Mikhailenko; Kazantseva; Arbuzova Russian Journal of General Chemistry, 2009 , vol. 79, # 11 p. 2453 - 2455

693-03-8 ~% 3084-50-2

文献：Christen; van der Linde; Hooge Recueil des Travaux Chimiques des Pays-Bas, 1959 , vol. 78, p. 161,163

上下游产品

上游产品  7
110-06-5 998-40-3 10544-50-0 15076-72-9
693-03-8 109-79-5 67-68-5
下游产品  2
998-40-3 814-29-9

海关

海关编码	2930909090
中文概述	2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%