106-75-2

• 常用中文名：二乙二醇双氯甲酸酯
• 常用英文名：Oxydiethylene bis(chloroformate)
• CAS号：106-75-2
• 分子式：C₆H₈Cl₂O₅
• 分子量：231.03100
• 相关类别： 化学试剂 有机试剂 酯类 酸酯类化合物
• 发布时间：2018-07-17 11:50:46
• 更新时间：2026-08-02 15:53:44

名称

• 中文名: 二乙二醇双氯甲酸酯
• 英文名: 2-(2-carbonochloridoyloxyethoxy)ethyl carbonochloridate
• 中文别名: 双氯甲酸二甘醇酯; 二乙二醇双氯甲酸酯/双肽酰氯; 氯酰烷酸二甘醇二酯; 氧基双(乙烷-2,1-二基) 二氯甲酸酯; 氯甲酸二甘醇酯; 双肽酰氯
• 英文别名: chloro-formic acid oxydiethylene ester; 2,2'-Oxybisethanol bis(chloroformate); diethylene glycol bischloroformate; bis(ethyl 2-chloroformate)ether; DIETHYLENEGLYCOLbis-CHLOROFORMATE(DECF); Diglycol chloroformate; Diglycol bis(chloroformate); 2-(2-Cbonochloridoyloxyethoxy)ethyl chloroformate; MFCD00018800; diglycolchlorformate; Bis[2-(chloroformyloxy)ethyl] ether; DEGbis(chloroformate); chloro-formicacioxydiethyleneester; Bis(chloridocbonic acid)(oxybisethylene) ester; Bis(chloroformic acid)(oxybisethylene) ester; Diglykol-bis(chlorameisensaeureester); 2-(2-cbonochloridoyloxyethoxy)ethyl cbonochloridate; oxydiethylenechloroformate; Oxybis(ethane-2,1-diyl) bis(cbonochloridate); Oxydiethylenbis(chlorformiat); chlorocbonic acid 2-(2-chlorocbonyloxyethoxy)ethyl ester; Carbonochloridic acid,oxydi-2,1-ethanediyl ester; Cbonochloridicacid,oxydi-2,1-ethanediylester; Diglycol chlorformate; EINECS 203-430-9; diglycolchloroformate; Oxydiethylene chloroformate; 1,5-bis((chlorocbonyl)oxy)-3-oxapentane; 2,2'-oxydiethanol bischloroformate; oxydiethane-2,1-diyl dichlorocarbonate; Diethylene glycol chloroformate; Bis(chloroformic acid)oxybisethylene ester; Cbonochloridic acid, C,C'-(oxydi-2,1-ethanediyl) ester; 2,2'-oxydiethyl chloroformate; chloro-formicacidiesterwithdiethyleneglycol; Diethylene glycol bis -chi or of or ma te; bis-(2-chlorocarbonyloxy-ethyl) ether; Bis-diethyleneglycolchloroformate; Formic acid, chloro-, diester with diethylene glycol; DIETHYLENE GLYCOL BIS(CHLOROFORMATE); oxydiethylene bis(chloroformate)

物化性质

• 密度: 1.48
• 沸点: 280ºC at 760 mmHg
• 分子式: C₆H₈Cl₂O₅
• 分子量: 231.03100
• 闪点: 118.2ºC
• 精确质量: 229.97500
• PSA: 61.83000
• LogP: 1.75380
• 折射率: 1.504
• 分子结构:

  1、 摩尔折射率：44.83

  2、 摩尔体积（cm³/mol）：163.6

  3、 等张比容（90.2K）：416.8

  4、 表面张力（dyne/cm）：42.0

  5、 极化率（10-24cm3）：17.77

• 计算化学:

  1.疏水参数计算参考值（XlogP）:2

  2.氢键供体数量:0

  3.氢键受体数量:5

  4.可旋转化学键数量:8

  5.互变异构体数量:无

  6.拓扑分子极性表面积61.8

  7.重原子数量:13

  8.表面电荷:0

  9.复杂度:154

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : LQ6700000 CHEMICAL NAME : Formic acid, chloro-, oxydiethylene ester CAS REGISTRY NUMBER : 106-75-2 BEILSTEIN REFERENCE NO. : 1812829 LAST UPDATED : 199806 DATA ITEMS CITED : 4 MOLECULAR FORMULA : C6-H8-Cl2-O5 MOLECULAR WEIGHT : 231.04 WISWESSER LINE NOTATION : GVO2O2OVG HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 813 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978 TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 169 ppm/1H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978 TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 3400 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978

安全

• 危害码 (欧洲): Xn: Harmful;N: Dangerous for the environment;
• 风险声明 (欧洲): R10
• 安全声明 (欧洲): S16-S26-S27-S45-S61-S23
• 危险品运输编码: 2742
• 海关编码: 2915900090

合成路线

75-44-5 111-46-6 ~% 106-75-2

文献：US2370568 , ;

上下游产品

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75-44-5 111-46-6
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111-44-4 111-46-6 142-22-3 6628-70-2
6946-51-6 6947-11-1 5396-39-4 5396-93-0
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海关

海关编码	2915900090
中文概述	2915900090. 其他饱和无环一元羧酸及其酸酐（酰卤、过氧）化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
监管条件	A.入境货物通关单 B.出境货物通关单
检验检疫	R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验
Summary	2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%