14283-05-7

• 常用中文名：硫酸四氨合铜(II)水合物
• 常用英文名：Tetraamminecopper sulphate
• CAS号：14283-05-7
• 分子式：CuH₁₄N₄O₅S
• 分子量：245.74600
• 发布时间：2018-05-22 08:00:00
• 更新时间：2024-01-02 18:47:32

名称

• 中文名: 四氨合铜硫酸盐N水
• 英文名: Tetraamminecopper(II) sulfate hydrate
• 中文别名: 四胺硫酸铜水合物
• 英文别名: Copper ammine sulfate; Tetraamminecopper Sulfate; Cupric sulfate ammoniate; COPPERTETRAMINESULPHATE; tetraamminecopper sulphate; Copper tetraammine sulfate

物化性质

• 沸点: 330ºC at 760mmHg
• 分子式: CuH₁₄N₄O₅S
• 分子量: 245.74600
• 精确质量: 244.99800
• PSA: 110.83000
• LogP: 0.97160
• 蒸汽压: 3.35E-05mmHg at 25°C
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：244.998091 Da

  8、标称质量：245 Da

  9、平均质量：245.746 Da

• 计算化学:

  1、 氢键供体数量：4

  2、 氢键受体数量：8

  3、 可旋转化学键数量：0

  4、 拓扑分子极性表面积（TPSA）：84.3

  5、 重原子数量：10

  6、 表面电荷：0

  7、 复杂度：62.2

  8、 同位素原子数量：0

  9、 确定原子立构中心数量：0

  10、 不确定原子立构中心数量：0

  11、 确定化学键立构中心数量：0

  12、 不确定化学键立构中心数量：0

  13、 共价键单元数量：6

• 更多:

  1. 性状：未确定

  2. 密度（g/mL,25/4℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Section 1: Product Identification Chemical Name:Tetraamminecopper (II) sulfatehydrate CAS Registry Number:14283-05-7 Formula:[Cu(NH3)4]SO4.XH2O EINECS Number:none Chemical Family:metal-ammine complexes Synonym:None Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14283-05-7100%1mg/m3 (as Cu)1mg/m3 (as Cu) Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:Causes slight to mild irritation of the eyes Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:Ingestion of copper compounds may lead to vomiting, exhaustion, anemia, convulsions and coma. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:none Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:blue xtl. Molecular Weight:227.72 Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:None Solubility in Water:soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:contact with strong oxidizing agents Incompatibility:oxidizing agents, azides and acetylene Decomposition Products:Ammonia, sulfur dioxide, and copper salts SECTION 11: Toxicological Information RTECS Data:No specific information available on this product. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:listed on the TSCA inventory SARA (Title 313):Title Compound: see Category Code N100 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 安全声明 (欧洲): 22-24/25

合成路线

7664-41-7 7758-99-8 ~% 14283-05-7

文献：Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 135, p. 534 - 537

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