12148-49-1

• 常用中文名：二氯化双(茚基)锆
• 常用英文名：dichlorobis(indenyl)zirconium(iv)
• CAS号：12148-49-1
• 分子式：C₁₈H₁₄Cl₂Zr
• 分子量：392.434
• 发布时间：2018-03-24 08:00:00
• 更新时间：2024-01-06 19:35:06

名称

• 中文名: 双茚基锆(VI)二氯化合物
• 英文名: dichlorobis(indenyl)zirconium(iv)
• 英文别名: 2,3-Dihydro-1H-indene-1,2,3,3a,7a-pentayl - dichlorozirconium (2:1)

物化性质

• 熔点: 239-243ºC(lit.)
• 分子式: C₁₈H₁₄Cl₂Zr
• 分子量: 392.434
• 精确质量: 389.951965
• LogP: 5.15480
• 外观性状: 固体
• 储存条件: 2-8°C， 避光， 惰性气体
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：389.951958 Da

  8、标称质量：390 Da

  9、平均质量：392.4338 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:2

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:21

  8.表面电荷:0

  9.复杂度:87

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:3

• 更多:

  1. 性状：未确定

  2. 密度（g/mL, 20 ℃ ）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：239-243

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC，1mmHg）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（20ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Name: Dichlorobis(indenyl)zirconium(IV) Material Safety Data Sheet Synonym: CAS: 12148-49-1 Section 1 - Chemical Product MSDS Name:Dichlorobis(indenyl)zirconium(IV) Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 12148-49-1 Dichlorobis(indenyl)zirconium(IV) unlisted Hazard Symbols: C Risk Phrases: 15 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Contact with water liberates extremely flammable gases. Causes burns.Moisture sensitive.Air sensitive. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas. Extinguishing Media: DO NOT USE WATER! In case of fire, use carbon dioxide, dry chemical powder or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Isolate area and deny entry. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use and store under nitrogen. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Keep away from water. Corrosives area. Store under nitrogen. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 12148-49-1: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 239-243 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C18H14Cl2Zr Molecular Weight: 392.43 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to air, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents, acids, bases, chemically active metals. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 12148-49-1 unlisted. LD50/LC50: Not available. Carcinogenicity: Dichlorobis(indenyl)zirconium(IV) - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: Corrosive solid, acidic, organic, n.o.s.* Hazard Class: 8 UN Number: 3261 Packing Group: III IMO Shipping Name: Corrosive solid, acidic, organic, n.o.s. Hazard Class: 8 UN Number: 3261 Packing Group: III RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 15 Contact with water liberates extremely flammable gases. R 34 Causes burns. Safety Phrases: S 7/8 Keep container tightly closed and dry. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 12148-49-1: No information available. Canada CAS# 12148-49-1 is listed on Canada's NDSL List. CAS# 12148-49-1 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 12148-49-1 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): C: Corrosive;
• 风险声明 (欧洲): R15
• 安全声明 (欧洲): 26-27-36/37/39-45
• 危险品运输编码: UN 3261 8/PG 3
• 海关编码: 2903999090

合成路线

23181-84-2 10026-11-6 ~33% 12148-49-1

文献：Piccolrovazzi, Nicoletta; Pino, Piero; Consiglio, Gamgattista; Sironi, Angelo; Moret Massimo Organometallics, 1990 , vol. 9, p. 3098 - 3105

10026-11-6 95-13-6 ~50% 12148-49-1

文献：Lapczuk-Krygier, Agnieszka; Baranowska, Katarzyna; Ponikiewski, Lukasz; Matern, Eberhard; Pikies, Jerzy Inorganica Chimica Acta, 2012 , vol. 387, p. 361 - 365

917-54-4 10294-34-5 10026-11-6 95-13-6 ~95% 详细

文献：Balboni, Davide; Camurati, Isabella; Ingurgio, Antonio Cascio; Guidotti, Simona; Focante, Francesca; Resconi, Luigi Journal of Organometallic Chemistry, 2003 , vol. 683, # 1 p. 2 - 10

7647-01-0 917-54-4 10026-11-6 95-13-6 ~90% 详细

文献：Balboni, Davide; Camurati, Isabella; Ingurgio, Antonio Cascio; Guidotti, Simona; Focante, Francesca; Resconi, Luigi Journal of Organometallic Chemistry, 2003 , vol. 683, # 1 p. 2 - 10

121009-93-6 173772-80-0 ~% 12148-49-1 406712-04-7

文献：Organometallics, , vol. 21, p. 920 - 923

10026-11-6 95-13-6 ~% 12148-49-1 173772-80-0

文献：Journal of Organometallic Chemistry, , vol. 683, # 1 p. 2 - 10

82163-52-8 10026-11-6 ~% 12148-49-1

文献：Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, , vol. 13, p. 1059 - 1066

上下游产品

上游产品  8
23181-84-2 10026-11-6 95-13-6 917-54-4
10294-34-5 7647-01-0 121009-93-6 82163-52-8
下游产品  2
23022-37-9 64465-03-8

海关

海关编码	2903999090
中文概述	2903999090 其他芳烃卤化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%