benzopinacolone

benzopinacolone Structure
benzopinacolone structure
Common Name benzopinacolone
CAS Number 466-37-5 Molecular Weight 348.436
Density 1.1±0.1 g/cm3 Boiling Point 498.4±14.0 °C at 760 mmHg
Molecular Formula C26H20O Melting Point 182-184 °C(lit.)
MSDS Chinese USA Flash Point 216.3±15.1 °C

Reactions of Acenaphthenequinone and Aceanthrenequinone with Arenes in Superacid.

Appl. Catal. A Gen. 336(1-2) , 128-132, (2008)

The hydroxyalkylation reactions of aceanthrenequinone (6) and acenapthenequinone (7) with a series of arenes have been studied. In reactions with the Br__nsted superacid CF(3)SO(3)H (triflic acid), the condensation products are formed in good yields (58-99%, ...

Chiral synthesis via organoboranes. 15. Selective reductions. 42. Asymmetric reduction of representative prochiral ketones with potassium 9-O-(1, 2: 5, 6-di-O-isopropylidene-. alpha.-D-glucofuranosyl)-9-boratabicyclo [3.3. 1] nonane. Brown HC, etal.

J. Org. Chem. 53(6) , 1231-38, (1988)