8-Methylquinoline N-oxide

8-Methylquinoline N-oxide Structure
8-Methylquinoline N-oxide structure
Common Name 8-Methylquinoline N-oxide
CAS Number 4053-38-7 Molecular Weight 159.18500
Density N/A Boiling Point N/A
Molecular Formula C10H9NO Melting Point N/A
MSDS Chinese USA Flash Point N/A

Gold-catalyzed highly regioselective oxidation of C-C triple bonds without acid additives: propargyl moieties as masked α,β-unsaturated carbonyls.

J. Am. Chem. Soc. 132 , 14070-14072, (2010)

Gold-catalyzed intermolecular oxidations of internal alkynes have been achieved with high regioselectivities using 8-alkylquinoline N-oxides as oxidants and in the absence of acid additives. Synthetically versatile α,β-unsaturated carbonyls are obtained in go...