oxosilylene
oxosilylene structure
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Common Name | oxosilylene | ||
|---|---|---|---|---|
| CAS Number | 10097-28-6 | Molecular Weight | 44.085 | |
| Density | 2.13 g/mL at 25 °C(lit.) | Boiling Point | 1880°C | |
| Molecular Formula | OSi | Melting Point | 1870 °C | |
| MSDS | Chinese USA | Flash Point | 1880°C | |
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Asymmetric fluorination of alpha-aryl acetic acid derivatives with the catalytic system NiCl2-Binap/R3SiOTf/2,6-lutidine.
Angew. Chem. Int. Ed. Engl. 46(28) , 5435-9, (2007)
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How to make the ionic Si-O bond more covalent and the Si-O-Si linkage a better acceptor for hydrogen bonding.
Inorg. Chem. 48(10) , 4384-93, (2009) Variation of a bond angle can tune the reactivity of a chemical compound. To exemplify this concept, the nature of the siloxane linkage (Si-O-Si), the most abundant chemical bond in the earth's crust, was examined using theoretical calculations on the molecul... |
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Silicon oxide nanoparticles reveal the origin of silicate grains in circumstellar environments.
Nano Lett. 6(6) , 1190-5, (2006) A synergistic effort combining experiments in beams and first principles theoretical investigations is used to propose mechanisms that could lead to the formation of silicates and nanoparticles with silicon-rich cores through agglomeration of SiO, an abundant... |
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Selective adhesion of Bacillus cereus spores on heterogeneously wetted silicon nanowires.
Langmuir 26(5) , 3479-84, (2010) The article reports on the selective adhesion of Bacillus cereus spores on patterned and heterogeneously wetted superhydrophobic silicon nanowires surfaces. Superhydrophilic patterns on superhydrophobic silicon nanowire (SiNW) surfaces were prepared by a stan... |
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Synthesis of gold-silica composite nanowires through solid-liquid-solid phase growth.
J. Nanosci. Nanotechnol. 3(4) , 341-6, (2003) Nanoscale wires of silicon oxide, and silicon oxide with embedded gold-silicide nanospheres, are synthesized by heating of a gold-coated silicon wafer at temperatures of 1000 degrees C or above, with the resulting wires having diameters ranging from 30 to 150... |
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Multiplexed protein patterns on a photosensitive hydrophilic polymer matrix.
Adv. Mater. 22(11) , 1242-6, (2010)
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[Photoluminescence from Er-doped silicon-rich silicon oxide film and Er-doped silicon-rich silicon nitride film and its annealing behavior].
Guang Pu Xue Yu Guang Pu Fen Xi 21(6) , 763-5, (2001) Room temperature photoluminescence (PL) with a peak at 1.54 microns was observed from silicon oxide, silicon-rich silicon oxide, silicon nitride and silicon-rich silicon nitride films, all doped with Er and grown by the magnetron sputtering technique. To dete... |
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SiOx layer as functional barrier in polyethylene terephthalate (PET) bottles against potential contaminants from post-consumer recycled PET.
Food Addit. Contam. Part A. Chem. Anal. Control. Expo. Risk Assess. 25(6) , 788-94, (2008) The barrier effect of a silicon oxide (SiOx) coating on the inner surface of PET bottles, in terms of the ability to reduce the migration of post-consumer compounds from the PET bottle wall into food simulants (3% acetic acid and 10% ethanol), was investigate... |
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Drug delivery observation of hydrophobe ferrofluid and magnetite nanoparticals by SPring-8 synchrotron radiation.
J. Nanosci. Nanotechnol. 11(10) , 8738-43, (2011) In this study, the composite magnetic nanoparticles of coated SiO nano film with about 8 nm size and high saturation magnetization value, were synthesized by liquid phase precipitation method. The magnetic nanoparticles can be dispersed in various liquid medi... |
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MRCI study on the spectroscopic parameters and molecular constants of the X1Σ+, a3Σ+, A1Π and C1Σ- electronic states of the SiO molecule.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 87 , 96-105, (2012) The potential energy curves (PECs) of the X(1)Σ(+), a(3)Σ(+), A(1)Π and C(1)Σ(-) electronic states of the SiO molecule are studied using an ab initio quantum chemical method. The calculations have been made employing the complete active space self-consistent ... |