9-Anthrylmethanol
9-Anthrylmethanol structure
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Common Name | 9-Anthrylmethanol | ||
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| CAS Number | 1468-95-7 | Molecular Weight | 208.255 | |
| Density | 1.2±0.1 g/cm3 | Boiling Point | 423.4±14.0 °C at 760 mmHg | |
| Molecular Formula | C15H12O | Melting Point | 162-164 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 196.3±15.9 °C | |
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Stable heterologous expression of hydroxysteroid sulphotransferase in Chinese hamster V79 cells and their use for toxicological investigations.
Chem. Biol. Interact. 92(1-3) , 119-28, (1994) Various benzylic alcohols are metabolically activated to electrophilic, potentially mutagenic and carcinogenic sulphuric acid esters. The involved sulphotransferases are not expressed in the cell lines in culture which are commonly used for mutagenicity testi... |
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Activation of promutagens by endogenous and heterologous sulfotransferases expressed in continuous cell cultures.
Toxicol. Lett. 72(1-3) , 13-21, (1994) Various environmental chemicals are metabolised to chemically reactive sulfuric acid esters, which may covalently bind to cellular macromolecules and induce mutations and tumours. This activation pathway is usually not taken into account in external xenobioti... |
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Self-assembled Pd6 open cage with triimidazole walls and the use of its confined nanospace for catalytic Knoevenagel- and Diels-Alder reactions in aqueous medium.
Chemistry 18(39) , 12322-9, (2012) The two-component self-assembly of a 90° Pd(II) acceptor and a triimidazole donor led to the formation of a water-soluble semi-cylindrical cage with a hydrophobic cavity, which was separately crystallized with hydrophilic- and hydrophobic guests. The parent c... |
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Stereoselective metabolism of 9-methyl-, 9-hydroxymethyl- and 9,10-dimethylanthracenes: absolute configurations and optical purities of trans-dihydrodiol metabolites.
Carcinogenesis 7(7) , 1135-41, (1986) Stereoselective metabolism of 9-methylanthracene (9-M-A), 9-hydroxymethylanthracene (9-OHM-A) and 9,10-dimethylanthracene (9,10-DM-A) by liver microsomes from untreated rats, and from rats pretreated with either 3-methylcholanthrene or phenobarbital was studi... |
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Stereoselective fungal metabolism of methylated anthracenes.
Appl. Environ. Microbiol. 56(3) , 661-8, (1990) The metabolism of 9-methylanthracene (9-MA), 9-hydroxymethylanthracene (9-OHMA), and 9,10-dimethylanthracene (9,10-DMA) by the fungus Cunninghamella elegans ATCC 36112 is described. The metabolites were isolated by high-performance liquid chromatography and c... |
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Synthesis, structural characterization and reactivity of aluminium complexes supported by benzotriazole phenoxide ligands: air-stable alumoxane as an efficient catalyst for ring-opening polymerization of L-lactide.
Dalton Trans. 40(9) , 1880-7, (2011) Aluminium complexes bearing sterically bulky benzotriazole-phenoxide ligands are synthesized and characterized structurally. The reaction of 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol ((CMe2Ph)BTP-H) or 2-(2H-benzotriazol-2-yl)-4,6-di-tert... |
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Rapid preparation of fluorescent 9-anthrylmethyl esters for fatty acid analysis of small amount of triacylglycerols.
Lipids 42(10) , 955-60, (2007) This paper proposes a one-step method for preparation of fluorescent 9-anthrylmethyl esters from triacylglycerols (TAG) ranging in amount from 0.1 to 5 microg. It involves base-catalyzed transesterification using potassium 9-anthracenemethoxide, prepared by p... |
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Experimental and DFT studies on the vibrational and electronic spectra of 9-anthracenemethanol.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 96 , 768-75, (2012) Vibrational spectral measurements were made for 9-anthracenemethanol. Optimized geometrical structure and harmonic vibration frequencies were computed based on ab initio and density functional theory B3LYP methods using 6-311G(**) and LANL2DZ basis sets. The ... |
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9-Sulfooxymethylanthracene is an ultimate electrophilic and carcinogenic form of 9-hydroxymethylanthracene.
Biochem. Biophys. Res. Commun. 251(1) , 239-43, (1998) The role of electrophilic hydroxymethyl sulfate esters in the metabolic activation, DNA-damage, mutagenicity, and complete carcinogenicity of polycyclic aromatic hydrocarbons has been elucidated considerably in recent years. The observations are in agreement ... |
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A universal ionization label for the APLI-(TOF)MS analysis of small molecules and polymers.
Angew. Chem. Int. Ed. Engl. 47 , 9989-9992, (2008)
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