(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl

(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl Structure
(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl structure
Common Name (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
CAS Number 99646-28-3 Molecular Weight 678.779
Density N/A Boiling Point 754.4±60.0 °C at 760 mmHg
Molecular Formula C48H40P2 Melting Point 255-257 °C
MSDS USA Flash Point 438.8±39.2 °C

Catalytic Approach for the Formation of Optically Active Allyl alpha-Amino Acids by Addition of Allylic Metal Compounds to alpha-Imino Esters.

J. Org. Chem. 64(13) , 4844-4849, (1999)

A new catalytic enantioselective approach for the formation of allyl alpha-amino acid derivatives by reaction of N-tosyl alpha-imino esters with allyl stannanes and silanes catalyzed by chiral copper(I) complexes has been developed. A series of different BINA...

Catalytic Asymmetric Aldol Reaction of Trimethoxysilyl Enol Ethers Using 2, 2'-Bis (di-p-tolylphosphino)-1, 1'-binaphthyl AgF Complex. Yanagisawa A, et al.

Bull. Chem. Soc. Jpn. 74(8) , 1477-84, (2001)

Asymmetric hydroformylation of vinyl acetate with BINAP-rhodium (I) complexes. Hoegaerts D and Jacobs PA.

Tetrahedron Asymmetry 10(15) , 3039-43, (1999)