2,6-Diethoxybenzoic acid

2,6-Diethoxybenzoic acid Structure
2,6-Diethoxybenzoic acid structure
Common Name 2,6-Diethoxybenzoic acid
CAS Number 82935-36-2 Molecular Weight 210.22600
Density 1.148g/cm3 Boiling Point 340ºC at 760 mmHg
Molecular Formula C11H14O4 Melting Point 131-135ºC(lit.)
MSDS Chinese USA Flash Point 130.1ºC

Methoxy-directed aryl-to-aryl 1,3-rhodium migration.

J. Am. Chem. Soc. 135(46) , 17270-3, (2013)

Through-space metal/hydrogen shift is an important strategy for transition-metal-catalyzed C-H bond activation. Here we describe the synthesis and characterization of a Rh(I) 2,6-dimethoxybenzoate complex that underwent stoichiometric rearrangement via a high...