3,3-Dimethyl-1,5-dioxaspiro(5.5)undecan-9-one

3,3-Dimethyl-1,5-dioxaspiro(5.5)undecan-9-one Structure
3,3-Dimethyl-1,5-dioxaspiro(5.5)undecan-9-one structure
Common Name 3,3-Dimethyl-1,5-dioxaspiro(5.5)undecan-9-one
CAS Number 69225-59-8 Molecular Weight 198.259
Density 1.1±0.1 g/cm3 Boiling Point 295.4±40.0 °C at 760 mmHg
Molecular Formula C11H18O3 Melting Point 45-50 °C(lit.)
MSDS Chinese USA Flash Point 123.3±13.8 °C

Carbanion-induced base-catalyzed synthesis of 1H-isothiochromenes, benzo[c]thiochromenes through ring-transformation reactions of 6-aryl-2H-pyran-2-ones.

J. Org. Chem. 66(16) , 5333-7, (2001)

An innovative approach to the one-pot synthesis of highly functionalized 3,4-dihydro-1H-isothiochromenes (3), 6H-benzo[c]thiochromenes (5, 6), 6H-benzo[c]chromenes (8), and 2,3-dihydro-1-benzothiophenes (10, 11) is delineated from the reaction of a suitably f...