(5H-dibenzo[a,d]cycloheptene-5-yl)diphenylphosphane
![(5H-dibenzo[a,d]cycloheptene-5-yl)diphenylphosphane Structure](https://image.chemsrc.com/caspic/176/210969-23-6.png)
(5H-dibenzo[a,d]cycloheptene-5-yl)diphenylphosphane structure
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Common Name | (5H-dibenzo[a,d]cycloheptene-5-yl)diphenylphosphane | ||
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| CAS Number | 210969-23-6 | Molecular Weight | 376.42900 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C27H21P | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | N/A | |
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Ethanol as hydrogen donor: highly efficient transfer hydrogenations with rhodium(I) amides.
Angew. Chem. Int. Ed. Engl. 47 , 3245-3249, (2008)
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Heterolytic splitting of hydrogen with rhodium(I) amides.
Angew. Chem. Int. Ed. Engl. 44 , 6318-6323, (2005)
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Electromeric rhodium radical complexes.
Angew. Chem. Int. Ed. Engl. 49 , 385-389, (2010)
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Amine olefin rhodium(I) complexes: pKa and NH bond strength.
Chem. Commun. (Camb.) 24 , 2820-2821, (2004) A combination of the rigid bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine (trop(2)NH) and 5-amino-5H-dibenzo[a,d]cycloheptene (tropNH(2)) ligand allowed the synthesis of the stable pentacoordinated 18 electron amine olefin rhodium(i) complex [Rh(trop(2)NH)(tropNH(... |
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Chiral Rhodium(I) and Iridium(I) Amino-Olefin Complexes:? pKa, N-H Bond Dissociation Energy, and Catalytic Transfer Hydrogenation Maire, P., et al.
Organometallics 24 , 3207-3218, (2005)
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Catalyzed Dehydrogenative Coupling of Primary Alcohols with Water, Methanol, or Amines Zweifel, T., et al.
Angew. Chem. Int. Ed. Engl. 49 , 559-563, (2009)
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