3'-Chloropropiophenone

3'-Chloropropiophenone Structure
3'-Chloropropiophenone structure
Common Name 3'-Chloropropiophenone
CAS Number 34841-35-5 Molecular Weight 168.62
Density 1.1±0.1 g/cm3 Boiling Point 246.8±0.0 °C at 760 mmHg
Molecular Formula C9H9ClO Melting Point 45-47 °C(lit.)
MSDS USA Flash Point 122.7±13.7 °C

Highly enantioselective catalytic phenylation of ketones with a constrained geometry titanium catalyst.

Org. Lett. 5(20) , 3641-4, (2003)

[reaction: see text] The catalytic asymmetric addition of phenyl groups from diphenylzinc to ketones is reported. The catalyst, generated from a dihydroxy bis(sulfonamide) ligand and titanium tetraisopropoxide, gives good to excellent enantioselectivities wit...