1-diphenylphosphino-1'-(di-tert-butylph&

1-diphenylphosphino-1'-(di-tert-butylph& Structure
1-diphenylphosphino-1'-(di-tert-butylph& structure
Common Name 1-diphenylphosphino-1'-(di-tert-butylph&
CAS Number 95408-38-1 Molecular Weight 514.39900
Density N/A Boiling Point N/A
Molecular Formula C30H36FeP2 Melting Point 75-79ºC(lit.)
MSDS USA Flash Point N/A

Endo-selective Pd-catalyzed silyl methyl Heck reaction.

J. Am. Chem. Soc. 136(52) , 17926-9, (2014)

A palladium (Pd)-catalyzed endo-selective Heck reaction of iodomethylsilyl ethers of phenols and aliphatic alkenols has been developed. Mechanistic studies reveal that this silyl methyl Heck reaction operates via a hybrid Pd-radical process and that the silic...