![]() Tetrabutylammonium hexafluorophosphate structure
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Common Name | Tetrabutylammonium hexafluorophosphate | ||
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CAS Number | 3109-63-5 | Molecular Weight | 387.42800 | |
Density | N/A | Boiling Point | 242-246 °C | |
Molecular Formula | C16H36F6NP | Melting Point | 244-246 °C(lit.) | |
MSDS | Chinese USA | Flash Point | N/A |
Astaxanthin diferulate as a bifunctional antioxidant.
Free Radic. Res. 49(1) , 102-11, (2014) Astaxanthin when esterified with ferulic acid is better singlet oxygen quencher with k2 = (1.58 ± 0.1) 10(10) L mol(-1)s(-1) in ethanol at 25°C compared with astaxanthin with k2 = (1.12 ± 0.01) 10(9) L mol(-1)s(-1). The ferulate moiety in the astaxanthin dies... |
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Cyclometalated iridium(III) bipyridyl-phenylenediamine complexes with multicolor phosphorescence: synthesis, electrochemistry, photophysics, and intracellular nitric oxide sensing.
ChemMedChem 9(6) , 1316-29, (2014) We present a new class of phosphorescent cyclometalated iridium(III) bipyridyl-phenylenediamine complexes [Ir(N^C)2 (bpy-DA)](PF6 ) (bpy-DA=4-(N-(2-amino-5-methoxyphenyl)aminomethyl)-4'-methyl-2,2'-bipyridine; HN^C=2-(2,4-difluorophenyl)pyridine (Hdfppy) (1 a... |
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A quantitative assay for reductive metabolism of a pesticide in fish using electrochemistry coupled with liquid chromatography tandem mass spectrometry.
Environ. Sci. Technol. 49(7) , 4450-7, (2015) This is the first study to use electrochemistry to generate a nitro reduction metabolite as a standard for a liquid chromatography-mass spectrometry-based quantitative assay. This approach is further used to quantify 3-trifluoromethyl-4-nitrophenol (TFM) redu... |
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Electrochemical nucleophilic synthesis of di-tert-butyl-(4-[18F]fluoro-1,2-phenylene)-dicarbonate.
Appl. Radiat. Isot. 92 , 52-7, (2014) An electrochemical method with the ability to conduct (18)F-fluorination of aromatic molecules through direct nucleophilic fluorination of cationic intermediates is presented in this paper. The reaction was performed on a remote-controlled automatic platform.... |
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Electrochemical behaviour of new dimeric esters and amides derived from caffeic acid in dimethylsulfoxide.
Org. Biomol. Chem. 12(31) , 5981-9, (2014) The electrochemical oxidation in DMSO of four new derivatives of caffeic acid (CA), two dimeric amides and two dimeric esters, is reported in this article. Although all of them contain two caffeoyl electroactive moieties in their structures, small differences... |
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New insights into the chemistry of di- and trimetallic iron dithiolene derivatives. Structural, Mössbauer, magnetic, electrochemical and theoretical studies.
Dalton Trans. 43(35) , 13187-95, (2014) Reaction of Fe3(CO)12 with 1,2-dithiolene HSC6H2Cl2SH affords a mixture of complexes [Fe2(CO)6(μ-SC6H2Cl2S)] 1, [Fe2(SC6H2Cl2S)4] 2 and [Fe3(CO)7(μ3-SC6H2Cl2S)2] 3. In the course of the reaction the trimetallic cluster 3 is first formed and then converted int... |
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Metal effects on ligand non-innocence in Group 5 complexes of the redox-active [ONO] pincer ligand.
Dalton Trans. 43(48) , 17991-8000, (2014) Isostructural vanadium, niobium and tantalum complexes of bis(3,5-di-tert-butyl-2-phenol)amine ([ONO]H3), were prepared and characterized to evaluate the impact of the metal ion on redox-activity of the ligand platform. New vanadium and niobium complexes with... |
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M.M. Baizer
Organic Electrochemistry New York, 1973, p. 228
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