(Acetylmethylene)triphenylphosphorane
(Acetylmethylene)triphenylphosphorane structure
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Common Name | (Acetylmethylene)triphenylphosphorane | ||
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| CAS Number | 1439-36-7 | Molecular Weight | 318.349 | |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 478.5±28.0 °C at 760 mmHg | |
| Molecular Formula | C21H19OP | Melting Point | 203-205 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 243.2±24.0 °C | |
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Cyclobutanones through SNi' ring closure, a mechanistic study.
J. Org. Chem. 72 , 2427, (2007) Mechanistic studies on the intramolecular nucleophilic substitution with allylic rearrangement (SNi' reaction) and a new stereoselective access to substituted cyclobutanones are reported. 4,4-Dialkyl-5-oxohex-2E-en-1-yl methanesulfonates 4 were converted to 2... |
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Synthesis , 1359, (2007)
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