Benzonitrile-dichloropalladium (2:1)

Benzonitrile-dichloropalladium (2:1) Structure
Benzonitrile-dichloropalladium (2:1) structure
Common Name Benzonitrile-dichloropalladium (2:1)
CAS Number 14220-64-5 Molecular Weight 383.57
Density N/A Boiling Point 191.1ºC at 760 mmHg
Molecular Formula C14H10Cl2N2Pd Melting Point 131 °C(lit.)
MSDS USA Flash Point 71.7ºC

Palladium-catalyzed stereoselective formation of alpha-O-glycosides.

Org. Lett. 9 , 3173, (2007)

A novel method for palladium-catalyzed stereoselective formation of alpha-O-glycosides has been developed. This strategy relies on the palladium-biaryl phosphine catalyst-glycal donor complexation to control the anomeric selectivity. It does not depend on the...

Alkynylation of alpha-halocarbonyl compounds--a stille-type cross-coupling for the formation of C(sp)-C(sp3) bonds under neutral conditions.

Chem. Commun. (Camb.) , 2342, (2007)

A direct alkynylation of readily available alpha-halo esters and amides with high yields is described herein; a distinct switch from diyne formation to alkynylation products was attained under neutral conditions.

Synthesis , 803, (1992)