Terephthalonitrile

Terephthalonitrile Structure
Terephthalonitrile structure
Common Name Terephthalonitrile
CAS Number 623-26-7 Molecular Weight 128.131
Density 1.2±0.1 g/cm3 Boiling Point 289.6±23.0 °C at 760 mmHg
Molecular Formula C8H4N2 Melting Point 221-225 °C(lit.)
MSDS Chinese USA Flash Point 142.8±16.5 °C

Mechanism of back electron transfer in an intermolecular photoinduced electron transfer reaction: solvent as a charge mediator.

ChemPhysChem 15(14) , 2945-50, (2014)

Back electron transfer (BET) is one of the important processes that govern the decay of generated ion pairs in intermolecular photoinduced electron transfer reactions. Unfortunately, a detailed mechanism of BET reactions remains largely unknown in spite of th...

A study of a moleculartweezer host-guest system by a combination of quantum-chemical calculations and solid-state NMR experiments.

Solid State Nucl. Magn. Reson. 22(2-3) , 128-53, (2002)

A study of a host-guest system consisting of a naphthalene-spaced tweezer with a 1,4 dicyanobenzene guest molecule is presented. The complex is investigated using a combination of quantum-chemical calculations and solid-state NMR experiments. The advantages o...

Thermal degradation of polyester coating powders: 1,4-dicyanobenzene as an occupational marker compound.

Analyst 114(9) , 1009-12, (1989)

A method for the determination of emissions in workroom air as a result of the thermal degradation of polyester coating powders is described. The method is based on the determination of certain marker compounds only. Polyester coating powders were degraded th...

Metallization of ultra-thin, non-thiol SAMs with flat-lying molecular units: Pd on 1, 4-dicyanobenzene.

ChemPhysChem 11(13) , 2951-6, (2010)

Self-assembled monolayers of 1,4-dicyanobenzene on Au(111) electrodes are studied by cyclic voltammetry, in-situ STM and ex-situ XPS. High-resolution STM images reveal a long-range order of propeller-like assemblies each of which consists of three molecules, ...

Synthesis and photophysics of novel 8-hydroxyquinoline aluminum metal complex with fluorene units.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 68(3) , 646-50, (2007)

A novel luminescent metal complex, (MQPF)3Al2, with 8-hydroxyquinoline aluminum and 9,9-diphenylfluorene was synthesized. The optical properties were investigated by UV-vis absorption and fluorescence emission spectra. The results showed that the luminescence...

Magnetic field effect on the exciplex between all-s-trans- 1,4-diphenylbuta- 1,3-diene and 1,4-dicyanobenzene: a comparative study with other alpha,omega-diphenyl polyenes.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 57A(5) , 1103-10, (2001)

The exciplex between all-s-trans-1,4-diphenylbuta-1,3-diene and 1,4-dicyanobenzene has been studied by steady state fluorescence along with the magnetic field effect (MFE) and compared with the other alpha,omega-diphenyl polyenes. The exciplex formation and m...

Influence of steric factors on exciplex energy and magnetic field effect.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 60(1-2) , 97-102, (2004)

With the advent of spin chemistry, magnetic field effect (MFE) on exciplex luminescence has emerged as an important domain of research. MFE is a diffusion controlled phenomenon and hence is solvent dielectric (epsilon) dependent. It maximizes at a particular ...