2-(Phenylsulfanyl)-1H-isoindole-1,3(2H)-dione

2-(Phenylsulfanyl)-1H-isoindole-1,3(2H)-dione Structure
2-(Phenylsulfanyl)-1H-isoindole-1,3(2H)-dione structure
Common Name 2-(Phenylsulfanyl)-1H-isoindole-1,3(2H)-dione
CAS Number 14204-27-4 Molecular Weight 255.292
Density 1.4±0.1 g/cm3 Boiling Point 432.2±28.0 °C at 760 mmHg
Molecular Formula C14H9NO2S Melting Point 160-163ºC(lit.)
MSDS Chinese USA Flash Point 215.2±24.0 °C

Catalytic asymmetric sulfenylation of unprotected 3-substituted oxindoles.

Org. Lett. 14(11) , 2726-9, (2012)

Catalytic asymmetric sulfenylation of unprotected 3-substituted oxindoles has been developed via cooperative catalysis of a chiral N,N'-dioxide-Sc(OTf)(3) complex and a Brønsted base. Utilizing readily available N-(phenylthio)phthalimide as the sulfur source,...

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As N-sulfenyl imines (e.g., RR'C=N-SAr) can be readily transformed to their N-sulfinyl imines (RR'C=N-SOAr), N-sulfonyl imines (RR'C=N-SO2Ar), and N-sulfonyl oxaziridines, the very mild procedure developed to convert ketoximes and secondary nitro derivatives ...