Chemische Berichte

Nucleophile Substitution von Nitrit in Nitrobenzolen, Nitrobiphenylen und Nitronaphthalinen

F Effenberger, M Koch, W Streicher

Index: Effenberger, Franz; Koch, Markus; Streicher, Willi Chemische Berichte, 1991 , vol. 124, # 1 p. 163 - 173

Full Text: HTML

Citation Number: 43

Abstract

Aromatic compounds, accessible only by multistep procedures, can be synthesized easily by nucleophilic substitution of nitrite in nitrobenzenes, nitrobiphenyls, and nitronaphthalenes. Thus, meta-substituted phenols 3.4, and 7 are obtained from 1, 3-dinitrobenzene (1) and meta-substituted nitrobenzenes 6, as well as 3, 5-disubstituted phenols 10 and 5-substituted resorcinol derivatives 11 from 3, 5-disubstituted nitrobenzenes 9. The unsymmetrically ...

 Related Synthetic Route
3-Fluoronitrobenzene Structure

402-67-5

3-Fluoronitrobenzene

Benzyl alcohol Structure

100-51-6

Benzyl alcohol

~88%

1-(BENZYLOXY)-3-NITROBENZENE Structure

24318-00-1

1-(BENZYLOXY)-3...

Benzyl 3-fluorophenyl ether Structure

72216-35-4

Benzyl 3-fluoro...

1,3-Dinitrobenzene Structure

99-65-0

1,3-Dinitrobenzene

potassium benzyloxide Structure

22379-62-0

potassium benzy...

~48%

1-(BENZYLOXY)-3-NITROBENZENE Structure

24318-00-1

1-(BENZYLOXY)-3...

1-Iodo-3-nitrobenzene Structure

645-00-1

1-Iodo-3-nitrob...

Benzyl alcohol Structure

100-51-6

Benzyl alcohol

~%

1-(Benzyloxy)-3-iodobenzene Structure

107623-21-2

1-(Benzyloxy)-3...

(4-iodophenyl)-(4-iodophenyl)imino-oxidoazanium Structure

19618-18-9

(4-iodophenyl)-...

Detail
3-Bromonitrobenzene Structure

585-79-5

3-Bromonitrobenzene

Benzyl alcohol Structure

100-51-6

Benzyl alcohol

~95%

1-(Benzyloxy)-3-bromobenzene Structure

53087-13-1

1-(Benzyloxy)-3...

4,4'-Dinitrobiphenyl Structure

1528-74-1

4,4'-Dinitrobiphenyl

Sodium Methylate Structure

124-41-4

Sodium Methylate

~98%

4-Methoxy-4'-nitrobiphenyl Structure

2143-90-0

4-Methoxy-4'-ni...

1,1'-Biphenyl,3,4'-dinitro- Structure

6311-43-9

1,1'-Biphenyl,3...

Sodium Methylate Structure

124-41-4

Sodium Methylate

~%

3-Methoxy-4'-nitro-1,1'-biphenyl Structure

107624-96-4

3-Methoxy-4'-ni...

4'-Methoxy-3-nitro-1,1'-biphenyl Structure

53059-31-7

4'-Methoxy-3-ni...

pnb Structure

92-93-3

pnb

Potassium methoxide Structure

865-33-8

Potassium methoxide

~81%

4-Methoxybiphenyl Structure

613-37-6

4-Methoxybiphenyl

2,4'-dinitro-1,1'-biphenyl Structure

606-81-5

2,4'-dinitro-1,...

Sodium Methylate Structure

124-41-4

Sodium Methylate

~93%

1-methoxy-2-(4-nitrophenyl)benzene Structure

6460-91-9

1-methoxy-2-(4-...

1,3-Dinitrobenzene Structure

99-65-0

1,3-Dinitrobenzene

Sodium isopropoxide Structure

683-60-3

Sodium isopropoxide

~27%

1-Isopropoxy-3-nitro-benzene Structure

88991-53-1

1-Isopropoxy-3-...

2,2'-Dinitrobiphenyl Structure

2436-96-6

2,2'-Dinitrobiphenyl

Sodium Methylate Structure

124-41-4

Sodium Methylate

~78%

1-(2-methoxyphenyl)-2-nitrobenzene Structure

6460-92-0

1-(2-methoxyphe...

3-Nitrochlorobenzene Structure

121-73-3

3-Nitrochlorobenzene

Benzyl alcohol Structure

100-51-6

Benzyl alcohol

~96%

1-chloro-3-phenylmethoxy-benzene Structure

24318-02-3

1-chloro-3-phen...

1,3-Dinitrobenzene Structure

99-65-0

1,3-Dinitrobenzene

~20%

2,4-Dinitrophenol Structure

51-28-5

2,4-Dinitrophenol

3-Nitrophenol Structure

554-84-7

3-Nitrophenol

1,3-Dinitrobenzene Structure

99-65-0

1,3-Dinitrobenzene

potassium t-butoxide Structure

865-47-4

potassium t-butoxide

~5%

2,4-Dinitrophenol Structure

51-28-5

2,4-Dinitrophenol

tert-Butyl-2,4-dinitrophenylether Structure

33696-26-3

tert-Butyl-2,4-...


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved