Calixarenes. 4. The synthesis, characterization, and properties of the calixarenes from p-tert-butylphenol

CD Gutsche, B Dhawan, KH No…

Index: Gutsche,C.D.; Dhawan,B.; No,K.H. Journal of the American Chemical Society, 1981 , vol. 103, p. 3782

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Citation Number: 734

Abstract

Abstract: The condensation of p-tert-butylphenol with formaldehyde to form cyclic oligomers has been investigated as part of a program concerned with the synthesis of enzyme model catalysts. The product of this condensation has been shown to comprise four identifiable materials which, because of their shape, have been named calixarenes (Greek calix, chalice; arene, indicating the incorporation of aromatic rings). The distribution of these ...

 Related Synthetic Route
Formaldehyde Structure

50-00-0

Formaldehyde

4-tert-Butylphenol Structure

98-54-4

4-tert-Butylphenol

~0%

5,11,17,23-Tetra-t-butyl-25,26,27,28-tetrahydroxycalix-4-arene Structure

157432-87-6

5,11,17,23-Tetr...

4-(tert-butyl)-2,6-bis{[5-(tert-butyl)-2-hydroxyphenyl]methyl}phenol Structure

810-52-6

4-(tert-butyl)-...

Detail
Formaldehyde Structure

50-00-0

Formaldehyde

4-tert-Butylphenol Structure

98-54-4

4-tert-Butylphenol

~0%

4-(tert-butyl)-2,6-bis{[5-(tert-butyl)-2-hydroxyphenyl]methyl}phenol Structure

810-52-6

4-(tert-butyl)-...

2-[(2-hydroxy-5-tert-butyl-phenyl)methyl]-4-tert-butyl-phenol Structure

799-13-3

2-[(2-hydroxy-5...

Detail
Formaldehyde Structure

50-00-0

Formaldehyde

4-tert-Butylphenol Structure

98-54-4

4-tert-Butylphenol

~0%

N/A Structure

189832-67-5

N/A

4-tert-Butylcalix[8]arene Structure

68971-82-4

4-tert-Butylcal...

Formaldehyde Structure

50-00-0

Formaldehyde

4-tert-Butylphenol Structure

98-54-4

4-tert-Butylphenol

~20%

4-tert-Butylcalix[8]arene Structure

68971-82-4

4-tert-Butylcal...

5,11,17,25-Tetrakis(2-methyl-2-propanyl)-21-oxapentacyclo[21.3.1.13,7.19,13.115,19]triaconta-1(27),3(30),4,6,9(29),10,12,15(28),16,18,23,25-dodecaene-27,28,29,30-tetrol Structure

72251-68-4

5,11,17,25-Tetr...

2,6-bis(hydroxymethyl)-4-tert-butylphenol Structure

2203-14-7

2,6-bis(hydroxy...

~8%

5,11,17,23-Tetra-t-butyl-25,26,27,28-tetrahydroxycalix-4-arene Structure

157432-87-6

5,11,17,23-Tetr...

N/A Structure

189832-67-5

N/A

4-tert-Butylcalix[8]arene Structure

68971-82-4

4-tert-Butylcal...

Detail
Formaldehyde Structure

50-00-0

Formaldehyde

4-tert-Butylphenol Structure

98-54-4

4-tert-Butylphenol

~33%

5,11,17,23-Tetra-t-butyl-25,26,27,28-tetrahydroxycalix-4-arene Structure

157432-87-6

5,11,17,23-Tetr...

4-(tert-butyl)-2,6-bis{[5-(tert-butyl)-2-hydroxyphenyl]methyl}phenol Structure

810-52-6

4-(tert-butyl)-...

Detail
Formaldehyde Structure

50-00-0

Formaldehyde

4-tert-Butylphenol Structure

98-54-4

4-tert-Butylphenol

~33%

4-(tert-butyl)-2,6-bis{[5-(tert-butyl)-2-hydroxyphenyl]methyl}phenol Structure

810-52-6

4-(tert-butyl)-...

2-[(2-hydroxy-5-tert-butyl-phenyl)methyl]-4-tert-butyl-phenol Structure

799-13-3

2-[(2-hydroxy-5...

Detail
Formaldehyde Structure

50-00-0

Formaldehyde

4-tert-Butylphenol Structure

98-54-4

4-tert-Butylphenol

~0%

4-tert-Butylcalix[8]arene Structure

68971-82-4

4-tert-Butylcal...

5,11,17,25-Tetrakis(2-methyl-2-propanyl)-21-oxapentacyclo[21.3.1.13,7.19,13.115,19]triaconta-1(27),3(30),4,6,9(29),10,12,15(28),16,18,23,25-dodecaene-27,28,29,30-tetrol Structure

72251-68-4

5,11,17,25-Tetr...


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