Chlorotrifluoroethylene-derived fluids. I. Model compound synthesis

KJL Paciorek, RH Kratzer, JH Nakahara, WH Lin…

Index: Paciorek, K. J. L.; Kratzer, R. H.; Nakahara, J. H.; Lin, W.-H. Journal of Fluorine Chemistry, 1991 , vol. 55, # 3 p. 271 - 282

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Abstract

Abstract A series of chlorofluoroalkanes having chlorines on adjacent carbon atoms has been prepared, ie nC 5 F 11 CFClCCl 3, nC 6 F 13 CFClCCl 3, nC 5 F 11 CFClCFCl 2, nC 6 F 13 CFClCFCl 2, nC 5 F 11 CFClCF 2 Cl, nC 2 F 5 CFClCFClC 3 F 7 and n-CF 3 CFClCFClC 4 F 9, by a combination of halogen exchange, dehalogenation and chlorine addition reactions. An attempt to synthesize nC 6 F 13 CFClCF 2 CFCl 2 by the coupling of ...