Russian journal of organic chemistry

Kinetics of the reaction of 4-nitrophenyl benzoates with 4-chlorophenol in the presence of potassium carbonate in dimethylformamide

IA Os'kina, VM Vlasov

Index: Os'kina; Vlasov Russian Journal of Organic Chemistry, 2006 , vol. 42, # 6 p. 865 - 872

Full Text: HTML

Citation Number: 10

Abstract

Abstract The effect of the substituent in the benzoyl group on the relative rate and activation parameters of transesterification of substituted 4-nitrophenyl benzoates with 4-chlorophenol in dimethylformamide in the presence of potassium carbonate was studied by the competing reaction technique. The whole series of benzoates showed the enthalpy-entropy compensation effect. 4-Nitrophenyl benzoates having electronacceptor substituents give ...