Interaction of nickel (0) complexes with allyl carboxylates, allyl ethers, allylic alcohols, and vinyl acetate.. pi.-Complex formation and oxidative addition to nickel …

T Yamamoto, J Ishizu, A Yamamoto

Index: Yamamoto, Takakazu; Ishizu, Junichi; Yamamoto, Akio Journal of the American Chemical Society, 1981 , vol. 103, # 23 p. 6863 - 6869

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Citation Number: 98

Abstract

Abstract: Interaction of various allylic compounds with bis (1, 5-~ yclooctadiene) nickel, N i (~ od)~, in the absence and presence of tertiary phosphines, causes cleavage of allyl-oxygen bonds. Allyl acetate reacts with N i (~ od)~ to afford a mixture of Ni (v3-C, H5), and Ni (OCOCH,), presumably through an intermediate, allylnickel acetate, followed by its disproportionation. Similar reactions in the presence of tertiary phosphine ligands, PR,( ...