European Journal of Organic Chemistry

Vanadium (I) Chloride and Lithium Vanadium (I) Dihydride as Selective Epimetallating Reagents for π??and σ??Bonded Organic Substrates

JJ Eisch, PO Fregene

Index: Eisch, John J.; Fregene, Paul O. European Journal of Organic Chemistry, 2008 , # 26 p. 4482 - 4492

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Citation Number: 15

Abstract

Abstract Subvalent vanadium (I) salts, of empirical formulas, VCl, vanadium (I) chloride and LiVH 2, lithium vanadium (I) dihydride, whose efficient preparation, structural constitution and mode of reaction toward certain organic substrates have been described in a preceding article, are here evaluated in their reactions toward a wide variety of π-and σ-bonded organic substrates, namely carbonyl, imine, azo, alkene, 1, 3-diene, nitrile π-bonds and C ...