European Journal of Organic Chemistry

Vanadium (I) Chloride and Lithium Vanadium (I) Dihydride as Selective Epimetallating Reagents for π??and σ??Bonded Organic Substrates

JJ Eisch, PO Fregene

Index: Eisch, John J.; Fregene, Paul O. European Journal of Organic Chemistry, 2008 , # 26 p. 4482 - 4492

Full Text: HTML

Citation Number: 15

Abstract

Abstract Subvalent vanadium (I) salts, of empirical formulas, VCl, vanadium (I) chloride and LiVH 2, lithium vanadium (I) dihydride, whose efficient preparation, structural constitution and mode of reaction toward certain organic substrates have been described in a preceding article, are here evaluated in their reactions toward a wide variety of π-and σ-bonded organic substrates, namely carbonyl, imine, azo, alkene, 1, 3-diene, nitrile π-bonds and C ...

 Related Synthetic Route
Benzonitrile Structure

100-47-0

Benzonitrile

~92%

2-Phenylacetophenone Structure

451-40-1

2-Phenylacetophenone

2'-Benzoylacetanilide Structure

85-99-4

2'-Benzoylaceta...

~87%

1H-Indole,2-methyl-3-phenyl- Structure

4757-69-1

1H-Indole,2-met...

N-(2-[Hydroxy(phenyl)methyl]phenyl)acetamide Structure

28586-49-4

N-(2-[Hydroxy(p...

9-Fluorenone Structure

486-25-9

9-Fluorenone

~10%

9-(9H-Fluoren-9-yliden)-9H-fluoren Structure

746-47-4

9-(9H-Fluoren-9...

N-Benzylidenemethanamine Structure

622-29-7

N-Benzylideneme...

~48%

(-)-(s,s)-dmpeda Structure

60509-62-8

(-)-(s,s)-dmpeda

N,N'-dimethyl-1,2-diphenylethane-1,2-diamine Structure

22751-68-4

N,N'-dimethyl-1...

N-Methylbenzylamine Structure

103-67-3

N-Methylbenzylamine

2-Bromoacetophenone Structure

70-11-1

2-Bromoacetophenone

~76%

Acetophenone Structure

98-86-2

Acetophenone

1,2-DIBENZOYLETHANE Structure

495-71-6

1,2-DIBENZOYLETHANE

adamantanone Structure

700-58-3

adamantanone

~99%

2-Adamantanol Structure

700-57-2

2-Adamantanol

Benzaldehyde Structure

100-52-7

Benzaldehyde

~29%

meso-1,2-Diphenyl-1,2-ethanediol Structure

579-43-1

meso-1,2-Diphen...

(+/-)-HYDROBENZOIN Structure

655-48-1

(+/-)-HYDROBENZOIN

Benzyl alcohol Structure

100-51-6

Benzyl alcohol

Benzene,1,1'-(1,3-butadiene-1,4-diyl)bis- Structure

886-65-7

Benzene,1,1'-(1...

~0%

1-phenyl-1,2,3,4-tetrahydronaphthalene Structure

3018-20-0

1-phenyl-1,2,3,...

1,4-diphenyl-1-butene Structure

14213-84-4

1,4-diphenyl-1-...

1,1'-(2-Butene-1,4-diyl)bisbenzene Structure

13657-49-3

1,1'-(2-Butene-...

Benzene,1,1'-(1,3-butadiene-1,4-diyl)bis- Structure

886-65-7

Benzene,1,1'-(1...

~82%

1-phenyl-1,2,3,4-tetrahydronaphthalene Structure

3018-20-0

1-phenyl-1,2,3,...

1,4-diphenyl-1-butene Structure

14213-84-4

1,4-diphenyl-1-...

1,1'-(2-Butene-1,4-diyl)bisbenzene Structure

13657-49-3

1,1'-(2-Butene-...


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