Introduction of Allyl and Prenyl Side??Chains into Aromatic Systems by Suzuki Cross??Coupling Reactions

…, SD Mandolesi, HG Schmalz…

Index: Gerbino, Dario C.; Mandolesi, Sandra D.; Schmalz, Hans-Guenther; Podesta, Julio C. European Journal of Organic Chemistry, 2009 , # 23 p. 3964 - 3972

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Citation Number: 36

Abstract

Abstract This paper reports some studies aiming at the developement of a general protocol useful for the synthesis of allyl-and prenylaromatic compounds. The first part deals with the preparation of boron reagents like arylboronic acids and their pinacol esters as well as of pinacol allyl-and prenylboronates. The second part of the paper is devoted to the use of these boron reagents in Suzuki–Miyaura cross-coupling reactions leading to allylation ...

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