Tetrahedron Letters

Direct conversion of α, β-unsaturated nitriles into cyanohydrins using Mn (dpm) 3 catalyst, dioxygen and phenylsilane

P Magnus, DA Scott, MR Fielding

Index: Magnus, Philip; Scott, David A.; Fielding, Mark R. Tetrahedron Letters, 2001 , vol. 42, # 25 p. 4127 - 4129

Full Text: HTML

Citation Number: 54

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Treatment of α,β-unsaturated nitriles with Mn(dpm) 3 (3 mol%), PhSiH 3 in isopropyl alcohol in the presence of oxygen resulted in reduction and α- and β-hydroxylation. ... Treatment of α,β-unsaturated nitriles 1 with Mn(dpm) 3 (cat.), phenylsilane in isopropyl alcohol in the presence of air resulted ...

~44%

~51%

~9%

~16%

Stereoselective Synthesis of Nipecotic Acid Derivatives via ...

[Shintani, Ryo; Murakami, Masataka; Hayashi, Tamio Organic Letters, 2009 , vol. 11, # 2 p. 457 - 459]

A facile one-pot benzylation of sodium enolates using triflu...

[Takuwa, Tomofumi; Minowa, Tomofumi; Fujisawa, Hidehiko; Mukaiyama, Teruaki Chemical and Pharmaceutical Bulletin, 2005 , vol. 53, # 5 p. 476 - 480]

Probing Persistent Intramolecular C− H··· X (X= O, S, Br, Cl...

[Fillion, Eric; Wilsily, Ashraf; Fishlock, Dan Journal of Organic Chemistry, 2009 , vol. 74, # 3 p. 1259 - 1267]

Sequential One-Pot Combination of Multireactions through Mul...

[Ramachary, Dhevalapally B.; Venkaiah, Chintalapudi; Reddy, Y. Vijayendar; Kishor, Mamillapalli Organic and Biomolecular Chemistry, 2009 , vol. 7, # 10 p. 2053 - 2062]

Photosilylation of electron-deficient alkenes by use of disi...

[Mizuno, Kazuhiko; Nakanishi, Kazuhisa; Chosa, Jun-ichi; Nguyen, Tien; Otsuji, Yoshio Tetrahedron Letters, 1989 , vol. 30, # 28 p. 3689 - 3692]