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27292-49-5

27292-49-5 structure
27292-49-5 structure
  • Name: 3-(4-Morpholinyl)phenol
  • Chemical Name: 3-morpholin-4-ylphenol
  • CAS Number: 27292-49-5
  • Molecular Formula: C10H13NO2
  • Molecular Weight: 179.216
  • Create Date: 2018-06-29 12:10:06
  • Modify Date: 2024-01-03 13:58:59

Name 3-morpholin-4-ylphenol
Synonyms m-Morpholinophenol
3-(Morpholin-4-yl)phenol
3-(4-morpholino)phenol
Phenol, 3-(4-morpholinyl)-
3-(4-morpholinyl)-phenol
3-Morpholinophenol
MFCD00051675
3-Morpholin-4-yl-phenol
m-N-morpholinophenol
N-(3-Hydroxyphenyl)morpholine
3-(4-Morpholinyl)phenol
Density 1.2±0.1 g/cm3
Boiling Point 362.6±37.0 °C at 760 mmHg
Melting Point 132ºC
Molecular Formula C10H13NO2
Molecular Weight 179.216
Flash Point 173.1±26.5 °C
Exact Mass 179.094635
PSA 32.70000
LogP 0.59
Vapour Pressure 0.0±0.8 mmHg at 25°C
Index of Refraction 1.575
Name: 3-Morpholinophenol 97% Material Safety Data Sheet
Synonym: N-(3-Hydroxyphenyl)morpholin
CAS: 27292-49-5
Section 1 - Chemical Product MSDS Name:3-Morpholinophenol 97% Material Safety Data Sheet
Synonym:N-(3-Hydroxyphenyl)morpholin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
27292-49-5 3-Morpholinophenol 97% unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 27292-49-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: pink
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 132 - 134 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H13NO2
Molecular Weight: 179.22

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, acids, bases, acid chlorides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 27292-49-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Morpholinophenol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 27292-49-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 27292-49-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 27292-49-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36
HS Code 2934999090

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Literature: WO2005/123054 A1, ; Page/Page column 30 ;

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Literature: Advanced Synthesis and Catalysis, , vol. 346, # 6 p. 611 - 616

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Literature: Advanced Synthesis and Catalysis, , vol. 346, # 6 p. 611 - 616

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Literature: Organic Letters, , vol. 5, # 19 p. 3515 - 3517

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Literature: DE720167 , ; DRP/DRBP Org.Chem.

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Literature: Industrial and Engineering Chemistry, , vol. 28, p. 656
HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%