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563-47-3

563-47-3 structure
563-47-3 structure
Name 3-Chloro-2-methylpropene
Synonyms clorurodimetallile
NCI-C54820
3-Chlor-2-methylpropen
Propene, 3-chloro-2-methyl
BETA-METHALLYL CHLORIDE
3-Cloro-2-metil-prop-1-ene
Isobutenyl chloride
Lercanidipine Impurity 21
1-propene,3-chloro-2-methyl
METHALLYL CHLORIDE
2-Methyl-3-chloropropene
Cloruro di metallile
EINECS 209-251-2
3-Chloro-2-methylprop-1-ene
2-methallylchloride
γ-Chloroisobutylene
gamma-Chloroisobutylene
3-Chloro-2-Methylpropene, .
Chlorure de methallyle
chloruedemethallyle(french)
2-Methyl-3-chloro-1-propene
Mac
3-chloro-2-methyl-propen
3-chloroisobu
3-chloro-2-methylprop-1-ene
3-Chlor-2-methyl-prop-1-en
1-CHLORO-2-METHYL-2-PROPENE
METHALLYLCHLORIDEBOTTOMS
3-CHLOROISOBUTYLENE
3-chloro-2-methyl-1-propen
chloruredemethallyle(french)
3-Chloroisobutene beta-Methallyl Chloride 2-Methylallyl Chloride 2-Methyl-2-propenyl Chloride
3-chloro-2-methyl
3-Chlor-2-methyl-1-propen
MFCD00000953
2-Methylallyl chloride, 2-Methylprop-2-en-1-yl chloride
3-Chloro-2-methylpropene-1
2-Methyl-allylchlorid
beta-Methylallyl chloride
chloruredemethallyle
2-METHYLALLYL CHLORIDE
3-CHLORO-2-METHYL-1-PROPENE
3-CHLORO-2-METHYL-1-PROPENE FOR SYNTHESI
Propene,3-chloro-2-methyl
3-CHLORO-2-METHYLPROPENE
beta-methylallylchloride
3-Chloro-2-Methylpropene, ., 1LT
2-Methyl-3-chloroprop-1-ene
3-Chloro-2-Methylpropylene
3-Chloro-2-methyl-1-propene,β-Methallyl chloride
3-Chloro-2-Methyl-1-propene contains ~250 ppM Pentaerythritol tetrakis(3,5-di-tert-butyl-4-hydroxyhydrocinnaMate) as stabilizer
2-(Chloromethyl)-1-propene
Methylallyl chloride
2-CHLORO-2-METHYL-1-PROPANE
Methallylchlorid
3-CHLOROISOBUTENE
Density 0.9±0.1 g/cm3
Boiling Point 72.4±9.0 °C at 760 mmHg
Melting Point -80 °C
Molecular Formula C4H7Cl
Molecular Weight 90.551
Flash Point -10.0±0.0 °C
Exact Mass 90.023628
LogP 2.20
Vapour density 3.12 (vs air)
Vapour Pressure 129.6±0.1 mmHg at 25°C
Index of Refraction 1.410
Water Solubility 0.5 g/L (20 ºC)

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UC8050000
CHEMICAL NAME :
Propene, 3-chloro-2-methyl-
CAS REGISTRY NUMBER :
563-47-3
BEILSTEIN REFERENCE NO. :
0878160
LAST UPDATED :
199801
DATA ITEMS CITED :
30
MOLECULAR FORMULA :
C4-H7-Cl
MOLECULAR WEIGHT :
90.56
WISWESSER LINE NOTATION :
G1Y1&U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human
DOSE/DURATION :
22000 ppm/10M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
848 mg/kg
TOXIC EFFECTS :
Behavioral - tremor Gastrointestinal - hypermotility, diarrhea Blood - hemorrhage
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
34 gm/m3/30M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3160 mg/kg
TOXIC EFFECTS :
Gastrointestinal - other changes Liver - other changes Blood - changes in spleen
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7 gm/kg/14D-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
19500 mg/kg/13W-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
16 gm/m3/1H/5W-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
10500 mg/kg/14D-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
81250 mg/kg/13W-I
TOXIC EFFECTS :
Liver - other changes Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis) Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
77250 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Endocrine - adrenal cortex tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
38625 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Gastrointestinal - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
51500 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Gastrointestinal - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
51500 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Gastrointestinal - tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
77250 mg/kg/2Y-I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Gastrointestinal - tumors Reproductive - Tumorigenic effects - testicular tumors
TYPE OF TEST :
Sex chromosome loss and nondisjunction

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
16 mg/L
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 13,133,1989 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 63,325,1995 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 63,325,1995 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 63,325,1995 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.3 mg/m3;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83971 No. of Facilities: 33 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 1683 (estimated)
Symbol GHS02 GHS05 GHS07 GHS09
GHS02, GHS05, GHS07, GHS09
Signal Word Danger
Hazard Statements H225-H302 + H332-H314-H317-H411
Precautionary Statements P210-P273-P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;
Risk Phrases R11;R20/22;R34;R43;R51/53
Safety Phrases S9-S16-S29-S36/37/39-S45-S61-S26
RIDADR UN 2554 3/PG 2
WGK Germany 2
RTECS UC8050000
Packaging Group II
Hazard Class 3
HS Code 2903299090
HS Code 2903299090
Summary 2903299090 other unsaturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%
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