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926-02-3

926-02-3 structure
926-02-3 structure

Name tert-butyl vinyl ether
Synonyms 2-ethenoxy-2-methylpropane
2-Methyl-2-(vinyloxy)propane
Propane, 2-(ethenyloxy)-2-methyl-
tert-butyl vinyl ether
2-(Ethenyloxy)-2-methylpropane
MFCD00048246
Tert-ButylVinylEther
Density 0.8±0.1 g/cm3
Boiling Point 75.0±0.0 °C at 760 mmHg
Melting Point 75-76ºC(lit.)
Molecular Formula C6H12O
Molecular Weight 100.159
Flash Point -21.3±10.8 °C
Exact Mass 100.088814
PSA 9.23000
LogP 1.74
Vapour Pressure 117.3±0.1 mmHg at 25°C
Index of Refraction 1.400
Storage condition Refrigerator (+4°C) + Flammables area
Stability Stable. Highly flammable. Incompatible with strong oxidizing agents. May be prone to the formation of peroxides when stored in contact with air.
Water Solubility Miscible with alcohol, carbon disulfide, chloroform and diethyl ether. Slightly miscible with water.
Name: tert-Butyl vinyl ether stabilized 98% Material Safety Data Sheet
Synonym:
CAS: 926-02-3
Section 1 - Chemical Product MSDS Name:tert-Butyl vinyl ether stabilized 98% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
926-02-3 tert-Butyl vinyl ether 98% unlisted
Hazard Symbols: F
Risk Phrases: 11 52/53

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Flammable liquid and vapor.
Containers may explode if exposed to fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.

Section 7 - HANDLING and STORAGE
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take precautionary measures against static discharges.
Storage:
Keep away from sources of ignition. Do not store in direct sunlight.
Store in a tightly closed container. Refrigerator/flammables.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 926-02-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless to yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: 105mbar @20 deg C
Viscosity: 0.41 mPa.s @20 deg C
Boiling Point: 78 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: 275 deg C ( 527.00 deg F)
Flash Point: -17 deg C ( 1.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.762
Molecular Formula: C6H12O
Molecular Weight: 100.16

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources, heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 926-02-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
tert-Butyl vinyl ether - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Daphnia: Daphnia: TLm = 15 ppm; 48h; .

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: ETHERS, N.O.S.*
Hazard Class: 3
UN Number: 3271
Packing Group: II
IMO
Shipping Name: ETHERS, N.O.S.
Hazard Class: 3
UN Number: 3271
Packing Group: II
RID/ADR
Shipping Name: ETHERS, N.O.S.
Hazard Class: 3
UN Number: 3271
Packing group: II

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 926-02-3: No information available.
Canada
CAS# 926-02-3 is listed on Canada's NDSL List.
CAS# 926-02-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 926-02-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger
Hazard Statements H225-H315
Precautionary Statements P210
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F,Xi
Risk Phrases R11
Safety Phrases S16-S26-S36
RIDADR UN 3271 3/PG 2
WGK Germany 3
Packaging Group II
Hazard Class 3.1
HS Code 2909199090

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926-02-3 structure

926-02-3

Literature: Potman; Janssen; Scheeren; Nivard Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3628 - 3634

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926-02-3

Literature: Journal of Organic Chemistry, , vol. 43, # 14 p. 2789 - 2792

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926-02-3

Literature: Journal of the American Chemical Society, , vol. 79, p. 2828,2829

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926-02-3

Literature: Journal of Organic Chemistry, , vol. 74, # 3 p. 1019 - 1028

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926-02-3

Literature: Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 1099,1102; engl. Ausg. S. 959, 960 Chem.Abstr., , p. 3001

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926-02-3 structure

926-02-3

Literature: Magnetic Resonance in Chemistry, , vol. 32, # 6 p. 353 - 357

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926-02-3 structure

926-02-3

Literature: Journal of Organic Chemistry, , vol. 24, p. 1752

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Detail
Literature: Journal of Organic Chemistry, , vol. 24, p. 1752
HS Code 2909199090
Summary 2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%