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111-96-6

111-96-6 structure
111-96-6 structure
Name diglyme
Synonyms diethyleneglycol dimethylether
Bis(2-methoxyethyl) Ether
diethylene glycol dimethyl ether
1-methoxyethoxy-2-methoxyethoxyethane
Dimethylcarbitol
DEG dibenzoate
bis-(2-methoxy ethyl)-ether
MFCD00008503
1-Methoxy-2-(2-methoxyethoxy)ethane
Benzo flex 2-45
diglyme
Bis-(2-benzoyloxy-aethyl)-aether
EINECS 203-924-4
diethyleneglycol dibenzoate
Bis(2-methoxyethyl) ether,AcroSeal,Extra Dry
bis-(2-benzoyloxy-ethyl)-ether
OXY BIS(2-ETHYL BENZOATE)
oxydiethylenedibenzoate
diethylenebenzylbenzoate
Ethane, 2,2'-oxybis[1-methoxy-
2-Methoxyethyl ether
DIGLYCOL DIBENZOATE
Dimethyldiglycol
Diaethylenglykol-dibenzoat
DEGDB
ethane, 1-methoxy-2-(2-methoxyethoxy)-
1O2O2O1
bis(methoxyethyl) ether
2,2-OXYBISETHANOLDIBENZOATE
Density 0.9±0.1 g/cm3
Boiling Point 159.8±0.0 °C at 760 mmHg
Melting Point −64 °C(lit.)
Molecular Formula C6H14O3
Molecular Weight 134.174
Flash Point 70.0±0.0 °C
Exact Mass 134.094299
PSA 27.69000
LogP -0.80
Vapour density 4.6 (vs air)
Vapour Pressure 3.2±0.2 mmHg at 25°C
Index of Refraction 1.394
Stability Stable. Combustible. Incompatible with strong oxidizing agents. May be air or light sensitive.
Water Solubility Miscible

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KN3339000
CHEMICAL NAME :
Ether, bis(2-methoxyethyl)
CAS REGISTRY NUMBER :
111-96-6
BEILSTEIN REFERENCE NO. :
1736101
LAST UPDATED :
199806
DATA ITEMS CITED :
20
MOLECULAR FORMULA :
C6-H14-O3
MOLECULAR WEIGHT :
134.20

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5400 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - ataxia Lungs, Thorax, or Respiration - respiratory depression
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
6 gm/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - ataxia Lungs, Thorax, or Respiration - respiratory depression
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
500 mg/kg
SEX/DURATION :
female 11 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - maternal-fetal exchange
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
13680 mg/kg
SEX/DURATION :
male 20 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct Reproductive - Paternal Effects - other effects on male
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
DOSE :
1100 ppm/6H
SEX/DURATION :
male 2 week(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
537 mg/kg
SEX/DURATION :
female 11 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - musculoskeletal system
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
2500 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - Central Nervous System Reproductive - Specific Developmental Abnormalities - cardiovascular (circulatory) system Reproductive - Specific Developmental Abnormalities - urogenital system
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
2500 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
5 gm/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth) Reproductive - Specific Developmental Abnormalities - musculoskeletal system
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1250 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1400 mg/kg
SEX/DURATION :
female 6-19 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Effects on Embryo or Fetus - fetal death Reproductive - Specific Developmental Abnormalities - musculoskeletal system
TYPE OF TEST :
Sex chromosome loss and nondisjunction
TYPE OF TEST :
Dominant lethal test

MUTATION DATA

TEST SYSTEM :
Rodent - mouse
DOSE/DURATION :
1000 ppm/5D (Continuous)
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB83-138198 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - T0698 No. of Facilities: 27 (estimated) No. of Industries: 1 No. of Occupations: 3 No. of Employees: 191 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - T0698 No. of Facilities: 13 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 207 (estimated) No. of Female Employees: 52 (estimated)
Symbol GHS02 GHS08
GHS02, GHS08
Signal Word Danger
Hazard Statements H226-H360
Supplemental HS May form explosive peroxides.
Precautionary Statements P201-P210-P280-P308 + P313-P370 + P378
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T:Toxic;
Risk Phrases R10;R19;R60;R61
Safety Phrases S53-S45
RIDADR UN 3271 3/PG 3
WGK Germany 1
RTECS KN3339000
Packaging Group III
Hazard Class 3
HS Code 2909199090
HS Code 2909199090
Summary 2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
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