Barban

Modify Date: 2024-01-08 20:01:50

Barban Structure
Barban structure
Common Name Barban
CAS Number 101-27-9 Molecular Weight 258.101
Density 1.4±0.1 g/cm3 Boiling Point 340.8±32.0 °C at 760 mmHg
Molecular Formula C11H9Cl2NO2 Melting Point 75-76ºC
MSDS Chinese USA Flash Point 159.9±25.1 °C
Symbol GHS07 GHS09
GHS07, GHS09
Signal Word Warning

 Use of Barban


Barban is a selective herbicide for wild oats.

 Names

Name barban
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 340.8±32.0 °C at 760 mmHg
Melting Point 75-76ºC
Molecular Formula C11H9Cl2NO2
Molecular Weight 258.101
Flash Point 159.9±25.1 °C
Exact Mass 257.001038
PSA 38.33000
LogP 3.87
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.607

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
FD7700000
CHEMICAL NAME :
Carbanilic acid, m-chloro-, 4-chloro-2-butynyl ester
CAS REGISTRY NUMBER :
101-27-9
BEILSTEIN REFERENCE NO. :
2376181
LAST UPDATED :
199706
DATA ITEMS CITED :
13
MOLECULAR FORMULA :
C11-H9-Cl2-N-O2
MOLECULAR WEIGHT :
258.11
WISWESSER LINE NOTATION :
G2UU2OVMR CG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
527 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
27400 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>1600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
527 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
322 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
23000 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
240 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
240 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
DNA repair
TEST SYSTEM :
Bacteria - Bacillus subtilis
DOSE/DURATION :
20 ug/disc
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 40,19,1976 *** REVIEWS *** TOXICOLOGY REVIEW DTTIAF Deutsche Tieraerztliche Wochenschrift. (Hanover, Fed. Rep. Ger.) V.1-77, 1893-1970. Volume(issue)/page/year: 80,485,1973 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

 Safety Information

Symbol GHS07 GHS09
GHS07, GHS09
Signal Word Warning
Hazard Statements H302-H317-H410
Precautionary Statements P273-P280-P501
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes Xn: Harmful;N: Dangerous for the environment;
Risk Phrases R22
Safety Phrases 24-36/37-60-61
RIDADR UN3077 9/PG 3
RTECS FD7700000
HS Code 2924299013

 Synthetic Route

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Barban Structure

Barban

CAS#:101-27-9

Literature: Journal of Organic Chemistry, , vol. 24, p. 2040

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Barban Structure

Barban

CAS#:101-27-9

Literature: Agricultural and Biological Chemistry, , vol. 44, # 6 p. 1237 - 1240

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Barban Structure

Barban

CAS#:101-27-9

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 33, p. 46 - 49,41 - 43

 Customs

HS Code 2924299013
Summary 2924299013. VAT:17.0%. Tax rebate rate:9.0%. Supervision conditions:S(import or export registration certificate for pesticides). MFN tariff:6.5%. General tariff:30.0%

 Articles15

More Articles
Synthesis of polyynes to model the sp-carbon allotrope carbyne.

Nature Chemistry 2(11) , 967-71, (2010)

Carbyne is an allotrope of carbon composed of sp-hybridized carbon atoms. Although its formation in the laboratory is suggested, no well-defined sample is described. Interest in carbyne and its potent...

Calcium-decorated carbyne networks as hydrogen storage media.

Nano Lett. 11(7) , 2660-5, (2011)

Among the carbon allotropes, carbyne chains appear outstandingly accessible for sorption and very light. Hydrogen adsorption on calcium-decorated carbyne chain was studied using ab initio density func...

The pressure tunning Raman and IR spectral studies on the multinuclear metal carbyne complexes.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 61(5) , 995-1000, (2005)

The Raman and infrared (IR) spectra of four tungsten metal carbyne complexes I, II, IV and V [Cl(CO)2(L)W[triple bond]CC6H4[triple bond](C[triple bond]CC6H4)n[triple bond]N[triple bond]C[triple bond]]...

 Synonyms

Carbamic acid, N-(3-chlorophenyl)-, 4-chloro-2-butyn-1-yl ester
4-Chlorobut-2-yn-1-yl (3-chlorophenyl)carbamate
Chlorinat
EINECS 202-930-4
MFCD00045297
4-Chloro-2-butyn-1-yl (3-chlorophenyl)carbamate
4-chlorobut-2-ynyl N-(3-chlorophenyl)carbamate
N-(m-chlorophenyl)carbamic acid,4-chloro-2-butynyl ester
Karbin
4-chlorobut-2-ynyl 3-chlorocarbanilate
Carbine
4-chloro-2-butynyl 3-chlorocarbanilate
Barban
4-chloro-2-butynyl N-(m-chlorophenyl)carbamate
Carbin
Barbanate
4-Chlorobut-2-ynyl 3-chlorophenylcarbamate
Barbamate
Chlorinate
4-chloro-2-butynyl m-chlorocarbanilate
4-chloro-2-butyn-1-yl N-(3-chlorophenyl)carbamate
Barbane
Carbyne (herbicide)
Carbyne
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