Glycidyl methacrylate

Modify Date: 2024-01-02 16:05:21

Glycidyl methacrylate Structure
Glycidyl methacrylate structure
 Common Name Glycidyl methacrylate
CAS Number 106-91-2 Molecular Weight 142.152
Density 1.1±0.1 g/cm3 Boiling Point 189.0 at 760 mmHg
Molecular Formula C7H10O3 Melting Point -52°C
MSDS Chinese USA Flash Point 76.1
Symbol GHS05 GHS06 GHS08
GHS05, GHS06, GHS08		 Signal Word Danger

 Names

Name Glycidyl methacrylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 189.0 at 760 mmHg
Melting Point -52°C
Molecular Formula C7H10O3
Molecular Weight 142.152
Flash Point 76.1
Exact Mass 142.062988
PSA 38.83000
LogP 1.39
Vapour Pressure 0.6±0.3 mmHg at 25°C
Index of Refraction 1.458
Storage condition Refrigerator
Stability Unstable. Light sensitive. May be stabilized with around 100ppm MEHQ. Refrigerate.
Water Solubility 0.5-1.0 g/100 mL at 20 ºC

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OZ4375000
CHEMICAL NAME :
Methacrylic acid, 2,3-epoxypropyl ester
CAS REGISTRY NUMBER :
106-91-2
BEILSTEIN REFERENCE NO. :
0002506
LAST UPDATED :
199806
DATA ITEMS CITED :
26
MOLECULAR FORMULA :
C7-H10-O3
MOLECULAR WEIGHT :
142.17
WISWESSER LINE NOTATION :
T3OTJ B1OVY1&U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
597 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1400 mg/m3/6H
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - other changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
390 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
1400 mg/m3/6H
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - other changes
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1400 mg/m3/6H
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - other changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
450 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
697 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
1400 mg/m3/6H
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - other changes
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2100 mg/kg/30D-I
TOXIC EFFECTS :
Behavioral - food intake (animal) Gastrointestinal - ulceration or bleeding from stomach Kidney, Ureter, Bladder - changes primarily in glomeruli
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
206 mg/m3/6H/26W-I
TOXIC EFFECTS :
Liver - changes in liver weight Endocrine - changes in spleen weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
40 ppm/6H/9D-I
TOXIC EFFECTS :
Sense Organs and Special Senses (Olfaction) - deviated nasal septum Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
206 mg/m3/6H/26W-I
TOXIC EFFECTS :
Brain and Coverings - other degenerative changes Cardiac - EKG changes not diagnostic of specified effects Blood - changes in erythrocyte (RBC) count
TYPE OF TEST :
Cytogenetic analysis

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Lung
DOSE/DURATION :
78 umol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 249,55,1991 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-THE NETHERLANDS:TWA 0.04 ppm (0.24 mg/m3) JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1341 No. of Facilities: 95 (estimated) No. of Industries: 2 No. of Occupations: 7 No. of Employees: 4002 (estimated)

 Safety Information

Symbol GHS05 GHS06 GHS08
GHS05, GHS06, GHS08
Signal Word Danger
Hazard Statements H302 + H332-H311-H314-H317-H341-H350-H360F-H370
Precautionary Statements P201-P260-P280-P305 + P351 + P338-P310
Target Organs Respiratory Tract
Hazard Codes Xn:Harmful
Risk Phrases R20/21/22;R36/38;R43
Safety Phrases S26-S28-S28A-S45-S36/37-S53
RIDADR UN 2810 6.1/PG 3
WGK Germany 2
RTECS OZ4375000
Packaging Group III
Hazard Class 8
HS Code 2916140000

 Synthetic Route

 Customs

HS Code 2916140000
Summary 2916140000. other esters of methacrylic acid. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:80.0%

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 Synonyms

Glycidyl Methacrylate
Methacrylic Acid Glycidyl Ester
2-((Methacryloxy)methyl)oxirane
oxiran-2-ylmethyl methacrylate
EINECS 203-441-9
Glycidyl methacrylate(GMA)
MFCD00005137
2,3-epoxypropyl methacrylate
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