Ethyl trifluoropyruvate structure
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Common Name | Ethyl trifluoropyruvate | ||
|---|---|---|---|---|
| CAS Number | 13081-18-0 | Molecular Weight | 170.087 | |
| Density | 1.3±0.1 g/cm3 | Boiling Point | 88.1±40.0 °C at 760 mmHg | |
| Molecular Formula | C5H5F3O3 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 8.1±22.2 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
| Name | Ethyl trifluoropyruvate |
|---|---|
| Synonym | More Synonyms |
| Density | 1.3±0.1 g/cm3 |
|---|---|
| Boiling Point | 88.1±40.0 °C at 760 mmHg |
| Molecular Formula | C5H5F3O3 |
| Molecular Weight | 170.087 |
| Flash Point | 8.1±22.2 °C |
| Exact Mass | 170.019073 |
| PSA | 43.37000 |
| LogP | 1.57 |
| Vapour Pressure | 62.0±0.2 mmHg at 25°C |
| Index of Refraction | 1.349 |
| Storage condition | Refrigerator |
| Symbol |
GHS02, GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H226-H302-H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US) |
| Hazard Codes | Xi:Irritant; |
| Risk Phrases | R10;R36/37/38 |
| Safety Phrases | S26-S37/39-S16 |
| RIDADR | UN 3272 3/PG 3 |
| WGK Germany | 3 |
| Packaging Group | III |
| Hazard Class | 3 |
| HS Code | 2918300090 |
|
~84%
Ethyl trifluoro... CAS#:13081-18-0 |
| Literature: E. I. Du Pont de Nemours and Company Patent: US4357282 A1, 1982 ; |
|
~82%
Ethyl trifluoro... CAS#:13081-18-0 |
| Literature: England, David C. Journal of Organic Chemistry, 1984 , vol. 49, # 21 p. 4007 - 4008 |
|
~37%
Ethyl trifluoro... CAS#:13081-18-0 |
| Literature: Francese, C.; Tordeux, M.; Wakselman, C. Tetrahedron Letters, 1988 , vol. 29, # 9 p. 1029 - 1030 |
|
~%
Ethyl trifluoro... CAS#:13081-18-0 |
| Literature: Gazzetta Chimica Italiana, , vol. 98, p. 265 - 276 |
|
~%
Ethyl trifluoro... CAS#:13081-18-0 |
| Literature: Journal of Organic Chemistry USSR (English Translation), , vol. 19, # 8 p. 1563 - 1564 Zhurnal Organicheskoi Khimii, , vol. 19, # 8 p. 1761 - 1762 |
| Precursor 6 | |
|---|---|
| DownStream 9 | |
| HS Code | 2918300090 |
|---|---|
| Summary | 2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0% |
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Organocatalytic enantioselective Friedel–Crafts alkylation of simple phenols with trifluoropyruvate. Zhao JL, et al.
Tetrahedron Lett. 49(9) , 1476-1479, (2008)
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Novel Enantiocomplementary C2-Symmetric Chiral Bis (imidazoline) Ligands: Highly Enantioselective Friedel–Crafts Alkylation of Indoles with Ethyl 3, 3, 3-Trifluoropyruvate. Nakamura S, et al.
Adv. Synth. Catal. 350(10) , 1443-1448, (2008)
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Synthesis of N-Heteroaryl (trifluoromethyl) hydroxyalkanoic Acid Esters by Highly Efficient Solid Acid-Catalyzed Hydroxyalkylation of Indoles and Pyrroles with Activated Trifluoromethyl Ketones. Abid M and Török B.
Adv. Synth. Catal. 347(14) , 1797-1803, (2005)
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| Ethyl 3,3,3-trifluoro-2-oxopropanoate |
| Ethyl trifluoropyruvate |
| Propanoic acid, 3,3,3-trifluoro-2-oxo-, ethyl ester |
| Trifluoropyruvic acid ethyl ester |
| Ethyl 2-oxo-3,3,3-trifluoropropanoate |
| Ethyl 3,3,3-trifluoropyruvate |
| MFCD00114935 |
| FXFFVVO2 |
| Ethyltrifluoropyruvate |