Methyl 3-aminocrotonate

Modify Date: 2024-01-02 06:13:38

Methyl 3-aminocrotonate Structure
Methyl 3-aminocrotonate structure
Common Name Methyl 3-aminocrotonate
CAS Number 14205-39-1 Molecular Weight 115.131
Density 1.0±0.1 g/cm3 Boiling Point 194.1±13.0 °C at 760 mmHg
Molecular Formula C5H9NO2 Melting Point 81-83 °C(lit.)
MSDS Chinese USA Flash Point 65.3±17.4 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name Methyl 3-aminocrotonate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 194.1±13.0 °C at 760 mmHg
Melting Point 81-83 °C(lit.)
Molecular Formula C5H9NO2
Molecular Weight 115.131
Flash Point 65.3±17.4 °C
Exact Mass 115.063332
PSA 52.32000
LogP -0.14
Vapour Pressure 0.4±0.4 mmHg at 25°C
Index of Refraction 1.457
Water Solubility insoluble

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302 + H332
Precautionary Statements P261-P301 + P312 + P330
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes Xn:Harmful
Risk Phrases R22;R36/37/38
Safety Phrases S37/39-S26
RIDADR NONH for all modes of transport
WGK Germany 3
RTECS EM9092500
HS Code 29224995

 Synthetic Route

~97%

Methyl 3-aminocrotonate Structure

Methyl 3-aminoc...

CAS#:14205-39-1

Literature: Cho; Ueda; Mizuno; Ishihara; Aisaka; Noguchi Chemical and Pharmaceutical Bulletin, 1989 , vol. 37, # 8 p. 2117 - 2121

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Methyl 3-aminocrotonate Structure

Methyl 3-aminoc...

CAS#:14205-39-1

Literature: Organic Letters, , vol. 14, # 13 p. 3506 - 3509

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Methyl 3-aminocrotonate Structure

Methyl 3-aminoc...

CAS#:14205-39-1

Literature: Bulletin de la Societe Chimique de France, , vol. <3> 13, p. 71

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Methyl 3-aminocrotonate Structure

Methyl 3-aminoc...

CAS#:14205-39-1

Literature: Monatshefte fuer Chemie, , vol. 28, p. 4 Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, , vol. <5> 14 I, p. 395 Chem. Zentralbl., , vol. 76, # I p. 1559 Chemische Berichte, , vol. 38, p. 1127 Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, , vol. <5> 14 I, p. 394 Chem. Zentralbl., , vol. 76, # I p. 1559

 Customs

HS Code 2922499990
Summary HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

 Articles2

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Quantitative reaction cascades of ninhydrin in the solid state.

Chemistry 8(3) , 594-600, (2002)

Crystalline ninhydrin (1) undergoes waste-free solid-state cascade reactions with dimedone, L-proline, three o-phenylenediamines, o-mercaptoaniline, two ureas, three thioureas, and methyl 3-aminocroto...

Synthesis of a new series of 4-aryl-1,4-dihydropyridines with calcium channel blocking and vasodilatory activity.

Pharmazie 61(5) , 400-5, (2006)

Synthesis of a new series of 4-aryl-1,4-dihydropyridines possessing potential calcium channel blocking activity along with good vasodilatory profile is reported. The compounds were synthesized using m...

 Synonyms

methyl 3-aminobut-2-enoate
(E)-methyl 3-aminobut-2-enoate
3-aminobut-2-enoic acid methyl ester
Methyl 3-aminocroton
MFCD06659463
(E)-3-Amino-but-2-enoic acid methyl ester
2-Butenoic acid, 3-amino-, methyl ester
Methyl 3-Amino-2-butenoate
Methyl (2E)-3-amino-2-butenoate
METHYL 4-AMINOCROTONATE
Methyl 3-iminobutyrate
3-Amino-2-Butenoic Acid Methyl Ester
3-Aminocrotonic Acid Methyl Ester
methyl3-aminocrotonoate
2-Butenoic acid, 3-amino-, methyl ester, (2E)-
EINECS 238-056-5
Nifedipine Impurity 5
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