Bis(triphenylphosphine)nickel(II)chloride

Modify Date: 2024-01-02 02:12:09

Bis(triphenylphosphine)nickel(II)chloride Structure
Bis(triphenylphosphine)nickel(II)chloride structure
Common Name Bis(triphenylphosphine)nickel(II)chloride
CAS Number 14264-16-5 Molecular Weight 654.17000
Density N/A Boiling Point 360ºCat 760 mmHg
Molecular Formula C36H30Cl2NiP2 Melting Point 250ºC (dec.)
MSDS Chinese USA Flash Point 181.7ºC
Symbol GHS07 GHS08
GHS07, GHS08
Signal Word Danger

 Names

Name Bis(triphenylphosphine)nickel(II) Dichloride
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 360ºCat 760 mmHg
Melting Point 250ºC (dec.)
Molecular Formula C36H30Cl2NiP2
Molecular Weight 654.17000
Flash Point 181.7ºC
Exact Mass 652.05500
PSA 27.18000
LogP 4.58310
Water Solubility insoluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QR6170000
CHEMICAL NAME :
Nickel, bis(triphenylphosphine)dichloro-
CAS REGISTRY NUMBER :
14264-16-5
LAST UPDATED :
199701
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C36-H30-Cl2-Ni-P2
MOLECULAR WEIGHT :
654.21
WISWESSER LINE NOTATION :
4P4&4 2 &G-NI-G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03119 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,178,1971 OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

 Safety Information

Symbol GHS07 GHS08
GHS07, GHS08
Signal Word Danger
Hazard Statements H317-H350
Precautionary Statements P201-P280-P308 + P313
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
Hazard Codes T:Toxic;
Risk Phrases R20/21/22;R34;R45
Safety Phrases S26-S36/37/39-S45-S53
RIDADR UN2923
WGK Germany 3
RTECS QR6170000
Packaging Group III
Hazard Class 6.1(b)
HS Code 29310095

 Synthetic Route

~14%

Bis(triphenylphosphine)nickel(II)chloride Structure

Bis(triphenylph...

CAS#:14264-16-5

Detail
Literature: Journal of the American Chemical Society, , vol. 125, # 14 p. 4350 - 4361

~%

Bis(triphenylphosphine)nickel(II)chloride Structure

Bis(triphenylph...

CAS#:14264-16-5

Literature: Ni: MVol.C2, 8.18.1, page 1041 - 1052

~%

Bis(triphenylphosphine)nickel(II)chloride Structure

Bis(triphenylph...

CAS#:14264-16-5

Literature: Ni: MVol.C2, 8.18.1, page 1041 - 1052

~%

Bis(triphenylphosphine)nickel(II)chloride Structure

Bis(triphenylph...

CAS#:14264-16-5

Detail
Literature: Inorganica Chimica Acta, , vol. 96, p. 179 - 186

~%

Bis(triphenylphosphine)nickel(II)chloride Structure

Bis(triphenylph...

CAS#:14264-16-5

Literature: Liebigs Annalen der Chemie, , vol. 560, p. 104 - 116

~%

Bis(triphenylphosphine)nickel(II)chloride Structure

Bis(triphenylph...

CAS#:14264-16-5

Detail
Literature: Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 21 p. 3075 - 3084

~%

Bis(triphenylphosphine)nickel(II)chloride Structure

Bis(triphenylph...

CAS#:14264-16-5

Literature: Bulletin of the Chemical Society of Japan, , vol. 46, p. 686

~%

Bis(triphenylphosphine)nickel(II)chloride Structure

Bis(triphenylph...

CAS#:14264-16-5

Literature: Bulletin of the Chemical Society of Japan, , vol. 53, # 1 p. 139 - 145

~%

Bis(triphenylphosphine)nickel(II)chloride Structure

Bis(triphenylph...

CAS#:14264-16-5

Literature: Ni: Org.Verb.2, 1.4.1.4, page 78 - 83

 Customs

HS Code 29310095

 Synonyms

EINECS 238-154-8
Bis(triphenylphosphine)nickel(II) dichloride
MFCD00009592
Bis(triphenylphosphine)nickel(II)chloride
NiCl2(PPh3)2
Dichlorobis(triphenylphosphine)nickel(II)
Nickel(II)bis(triphenylphosphine) dichloride
Phosphine, tributyl-, compd. with nickelchloride (2_1)