Dichloro(chloromethyl)methylsilane

Modify Date: 2024-01-02 16:55:41

Dichloro(chloromethyl)methylsilane Structure
Dichloro(chloromethyl)methylsilane structure
Common Name Dichloro(chloromethyl)methylsilane
CAS Number 1558-33-4 Molecular Weight 163.506
Density 1.2±0.1 g/cm3 Boiling Point 120.0±13.0 °C at 760 mmHg
Molecular Formula C2H5Cl3Si Melting Point <0°C
MSDS Chinese USA Flash Point 35.0±0.0 °C
Symbol GHS02 GHS05 GHS06
GHS02, GHS05, GHS06
Signal Word Danger

 Names

Name Chloromethyldichloromethylsilane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 120.0±13.0 °C at 760 mmHg
Melting Point <0°C
Molecular Formula C2H5Cl3Si
Molecular Weight 163.506
Flash Point 35.0±0.0 °C
Exact Mass 161.922607
LogP 3.41
Vapour density >1 (vs air)
Vapour Pressure 18.6±0.2 mmHg at 25°C
Index of Refraction 1.439
Storage condition 2-8°C
Water Solubility reacts

 Safety Information

Symbol GHS02 GHS05 GHS06
GHS02, GHS05, GHS06
Signal Word Danger
Hazard Statements H226-H314-H331-H335
Supplemental HS Reacts violently with water.
Precautionary Statements P261-P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive;
Risk Phrases R10;R14;R20;R34
Safety Phrases S26-S36/37/39-S45-S8-S16
RIDADR UN 2927 6.1/PG 2
WGK Germany 3
RTECS VV2160000
Packaging Group III
Hazard Class 3.2

 Synthetic Route

~97%

Dichloro(chloromethyl)methylsilane Structure

Dichloro(chloro...

CAS#:1558-33-4

Literature: Auner, N.; Grobe, J. Journal of Organometallic Chemistry, 1980 , vol. 188, # 2 p. 151 - 178

~87%

Dichloro(chloromethyl)methylsilane Structure

Dichloro(chloro...

CAS#:1558-33-4

Literature: Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 41, # 12 p. 1527 - 1534

~%

Dichloro(chloromethyl)methylsilane Structure

Dichloro(chloro...

CAS#:1558-33-4

Literature: Journal of the American Chemical Society, , vol. 67, p. 1810 - 1812

~11%

Dichloro(chloromethyl)methylsilane Structure

Dichloro(chloro...

CAS#:1558-33-4

Literature: Jukobovic, A. J.; Makarov, S. P.; etal. Doklady Akad. Nauk SSSR. (russ.) (2), 1950 , vol. 71, p. 303 - 303 C. I, 1951 , p. 2419 Full Text Show Details Gmelin Handbook: Si: MVol.C, 48, page 138 - 141

~42%

Dichloro(chloromethyl)methylsilane Structure

Dichloro(chloro...

CAS#:1558-33-4

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 51, # 5 p. 1207 - 1208,1021

~%

Detail
Literature: US2474578 , ; Journal of the American Chemical Society, , vol. 67, p. 1810,1812

~%

Detail
Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 59, # 5.1 p. 1057 - 1062,934 - 937

 Articles1

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Tridentate Lewis Acids Based on 1,3,5-Trisilacyclohexane Backbones and an Example of Their Host-Guest Chemistry.

Chemistry 21 , 12436-48, (2015)

Directed tridentate Lewis acids based on the 1,3,5-trisilacyclohexane skeleton with three ethynyl groups [CH2Si(Me)(C2H)]3 were synthesised and functionalised by hydroboration with HB(C6F5)2, yielding...

 Synonyms

(chloromethyl)dichloromethylsilane
ChloroMethyl(dichloro)Methylsilane
EINECS 216-319-5
Silane, dichloro(chloromethyl)methyl-
Cl2Si(CH2Cl)Me
MFCD00000874
Dichloro(chloromethyl)methylsilane
(chloromethyl)(methyl)dichlorosilane
(Chloromethyl)methyldichlorosilane
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