Benzamide,2-chloro-5-nitro-

Modify Date: 2024-01-15 03:02:11

Benzamide,2-chloro-5-nitro- Structure
Benzamide,2-chloro-5-nitro- structure
Common Name Benzamide,2-chloro-5-nitro-
CAS Number 16588-15-1 Molecular Weight 200.57900
Density 1.52 g/cm3 Boiling Point 299ºC at 760 mmHg
Molecular Formula C7H5ClN2O3 Melting Point 178 °C
MSDS N/A Flash Point 134.6ºC

 Names

Name 2-chloro-5-nitrobenzamide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.52 g/cm3
Boiling Point 299ºC at 760 mmHg
Melting Point 178 °C
Molecular Formula C7H5ClN2O3
Molecular Weight 200.57900
Flash Point 134.6ºC
Exact Mass 199.99900
PSA 88.91000
LogP 2.57060
Vapour Pressure 0.00122mmHg at 25°C
Index of Refraction 1.624

 MSDS

Name: 2-Chloro-5-nitrobenzamide 97% Material Safety Data Sheet
Synonym:
CAS: 16588-15-1
Section 1 - Chemical Product MSDS Name:2-Chloro-5-nitrobenzamide 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
16588-15-1 2-Chloro-5-nitrobenzamide 97% unlisted
Hazard Symbols: XN
Risk Phrases: 22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 16588-15-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: pale yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 183 - 185 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H5ClN2O3
Molecular Weight: 201

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Acids, bases, oxidizing agents, reducing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 16588-15-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Chloro-5-nitrobenzamide - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 16588-15-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 16588-15-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16588-15-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36/37/39
HS Code 2924299090

 Synthetic Route

~85%

Benzamide,2-chloro-5-nitro- Structure

Benzamide,2-chl...

CAS#:16588-15-1

Literature: US2014/57911 A1, ; Paragraph 0417; 0418 ;

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Benzamide,2-chloro-5-nitro- Structure

Benzamide,2-chl...

CAS#:16588-15-1

Literature: US5463122 A1, ;

~12%

Benzamide,2-chloro-5-nitro- Structure

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CAS#:16588-15-1

Literature: Synthetic Communications, , vol. 20, # 4 p. 563 - 571

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Benzamide,2-chloro-5-nitro- Structure

Benzamide,2-chl...

CAS#:16588-15-1

Literature: Journal of the Indian Chemical Society, , vol. 10, p. 353,357

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Benzamide,2-chloro-5-nitro- Structure

Benzamide,2-chl...

CAS#:16588-15-1

Literature: Liebigs Annalen der Chemie, , p. 29 - 37

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Benzamide,2-chloro-5-nitro- Structure

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CAS#:16588-15-1

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 19, p. 55

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Benzamide,2-chloro-5-nitro- Structure

Benzamide,2-chl...

CAS#:16588-15-1

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 19, p. 55

~%

Benzamide,2-chloro-5-nitro- Structure

Benzamide,2-chl...

CAS#:16588-15-1

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 19, p. 55

~%

Benzamide,2-chloro-5-nitro- Structure

Benzamide,2-chl...

CAS#:16588-15-1

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 19, p. 55

 Customs

HS Code 2924299090
Summary 2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

2-chloro-5-nitrobenzenecarboxamide
MFCD00088420
2-chloranyl-5-nitro-benzamide
2-chloro-5-nitro-benzoic acid amide
2-chloro-5-nitro-benzamide
2-Chlor-5-nitro-benzoesaeure-amid
Benzamide,2-chloro-5-nitro