(+)-Fenchol structure
|
Common Name | (+)-Fenchol | ||
---|---|---|---|---|
CAS Number | 2217-02-9 | Molecular Weight | 154.24900 | |
Density | 0.992g/cm3 | Boiling Point | 201ºC | |
Molecular Formula | C10H18O | Melting Point | 39-45ºC | |
MSDS | Chinese USA | Flash Point | 165 °F |
Name | (1S,3R,4R)-2,2,4-trimethylbicyclo[2.2.1]heptan-3-ol |
---|---|
Synonym | More Synonyms |
Density | 0.992g/cm3 |
---|---|
Boiling Point | 201ºC |
Melting Point | 39-45ºC |
Molecular Formula | C10H18O |
Molecular Weight | 154.24900 |
Flash Point | 165 °F |
Exact Mass | 154.13600 |
PSA | 20.23000 |
LogP | 2.19350 |
Vapour Pressure | 0.0693mmHg at 25°C |
Index of Refraction | 1.502 |
Synonym:1,3,3-Trimethyl-2-norbornano Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. Inhalation: May cause respiratory tract irritation. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 2217-02-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Crystals Color: Colorless Crystals Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 201 deg C @ 760.00mmHg Freezing/Melting Point: 39.00 - 45.00 deg C Autoignition Temperature: Not available. Flash Point: 73 deg C ( 163.40 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H18O Molecular Weight: 154.25 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, ignition sources, dust generation, excess heat, strong oxidants. Incompatibilities with Other Materials: Strong oxidizing agents, strong reducing agents, strong acids, acid chlorides, acid anhydrides. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 2217-02-9 unlisted. LD50/LC50: Not available. Carcinogenicity: (1R)-endo-(+)-Fenchol - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 2217-02-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 2217-02-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 2217-02-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
---|---|
Risk Phrases | 36/38 |
Safety Phrases | S22-S24/25 |
RIDADR | UN 1325 4.1/PG 2 |
WGK Germany | 3 |
Chocolate smells pink and stripy: Exploring olfactory-visual synesthesia.
Cogn Neurosci 6 , 77-88, (2015) Odors are often difficult to identify, and can be perceived either via the nose or mouth ("flavor"; not usually perceived as a "smell"). These features provide a unique opportunity to contrast concept... |
|
[GC-MS analysis and inhibitory activity of the essential oil extracted from the leaves of Lindera communis].
Zhong Yao Cai 22(3) , 128-31, (1999) The essential oil isolated from the dried leaves of Lindera communis was analyzed by means of gas chromatography-mass(GC-MS) technique, the structures of 23 chemical components were identified from it... |
|
Biosynthesis of monoterpenes. Enantioselectivity in the enzymatic cyclization of linalyl pyrophosphate to (-)-endo-fenchol.
J. Biol. Chem. 260(26) , 13901-8, (1985) The conversion of geranyl pyrophosphate to (-)-endo-fenchol is considered to proceed by the initial isomerization of the substrate to (-)-(3R)-linalyl pyrophosphate and the subsequent cyclization of t... |
EINECS 216-639-5 |
1,3,3-trimethyl-2-norbornanol |
MFCD00003760 |
(+)-Fenchol |