Glyphosine

Modify Date: 2024-01-02 15:17:11

Glyphosine Structure
Glyphosine structure
 Common Name Glyphosine
CAS Number 2439-99-8 Molecular Weight 263.080
Density 2.0±0.1 g/cm3 Boiling Point 668.4±65.0 °C at 760 mmHg
Molecular Formula C4H11NO8P2 Melting Point 263°C
MSDS Chinese USA Flash Point 358.0±34.3 °C
Symbol GHS05
GHS05		 Signal Word Danger

 Names

Name glyphosine
Synonym More Synonyms

 Chemical & Physical Properties

Density 2.0±0.1 g/cm3
Boiling Point 668.4±65.0 °C at 760 mmHg
Melting Point 263°C
Molecular Formula C4H11NO8P2
Molecular Weight 263.080
Flash Point 358.0±34.3 °C
Exact Mass 262.996002
PSA 175.22000
LogP -2.89
Vapour Pressure 0.0±4.4 mmHg at 25°C
Index of Refraction 1.594

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MB9120000
CHEMICAL NAME :
Glycine, N,N-bis(phosphonomethyl)-
CAS REGISTRY NUMBER :
2439-99-8
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C4-H11-N-O8-P2
MOLECULAR WEIGHT :
263.10
WISWESSER LINE NOTATION :
QPQO&1N1VQ1PQQO

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3925 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 3,60,1976/1977 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1920 mg/kg/24D-C
TOXIC EFFECTS :
Liver - changes in liver weight Endocrine - changes in thymus weight Immunological Including Allergic - decrease in humoral immune response
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 30,103,1984

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H318
Precautionary Statements P280-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R41
Safety Phrases S26-S2
RIDADR UN 3261 8/PG 3
WGK Germany 1
RTECS MB9120000
Packaging Group III
Hazard Class 8.0
HS Code 2931900042

 Synthetic Route

Formaldehyde structure

Formaldehyde

CAS#:50-00-0
Glycine structure

Glycine

CAS#:56-40-6

~77%

Glyphosine Structure

Glyphosine

CAS#:2439-99-8
Literature: STRAITMARK HOLDING AG; NOTTE, Patrick; PIRARD, Cedric Nicolas; LEMIN, David Patent: WO2010/136566 A1, 2010 ; Location in patent: Page/Page column 15 ;
N,N-bis((dimethoxyphosphinyl)methyl)glycine structure

N,N-bis((dimeth...

CAS#:123959-98-8

~85%

Glyphosine Structure

Glyphosine

CAS#:2439-99-8
Literature: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; INSTITUT NATIONAL DE LA SANTE ET DE LA RECHERCHE M; RHODIA UK LIMITED Patent: US2009/142316 A1, 2009 ; Location in patent: Page/Page column 116 ;
O-trimethylsilyl N,N-bis[bis(trimethylsiloxy)phosphorylmethyl]glycine structure

O-trimethylsily...

CAS#:178883-78-8

~92%

Glyphosine Structure

Glyphosine

CAS#:2439-99-8
Literature: Prishchenko, Andrey A.; Livantsov, Mikhail V.; Novikova, Olga P.; Livantsova, Ludmila I.; Petrosyan, Valery S. Heteroatom Chemistry, 2010 , vol. 21, # 6 p. 430 - 440
IMINO-BIS(METHYLPHOSPHONIC ACID) structure

IMINO-BIS(METHY...

CAS#:17261-34-6
Chloroacetic acid structure

Chloroacetic acid

CAS#:79-11-8

~61%

Glyphosine Structure

Glyphosine

CAS#:2439-99-8
Literature: Tsirul'nikova, N. V.; Temkina, V. Ya.; Sushitskaya, T. M.; Rykov, S. V. J. Gen. Chem. USSR (Engl. Transl.), 1981 , vol. 51, # 5 p. 1028 - 1035,859 - 864
2-(dimethoxyphosphorylmethylamino)acetic acid structure

2-(dimethoxypho...

CAS#:65886-96-6

~%

(Hydroxymethyl)phosphonic acid structure

(Hydroxymethyl)...

CAS#:2617-47-2
Glyphosine Structure

Glyphosine

CAS#:2439-99-8

Methyl Glyphosate structure

Methyl Glyphosate

CAS#:24569-83-3
Detail
Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 58, # 10 p. 2238 - 2242,1992 - 1996
IMINO-BIS(METHYLPHOSPHONIC ACID) structure

IMINO-BIS(METHY...

CAS#:17261-34-6
Sodium chloroacetate structure

Sodium chloroacetate

CAS#:3926-62-3

~%

Glyphosine Structure

Glyphosine

CAS#:2439-99-8
Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 60, # 4.1 p. 734 - 737,639 - 641

 Customs

HS Code 2931900042
Summary 2931900042 2-(bis(phosphonomethyl)amino)acetic acid。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

 Articles6

More Articles
Structure-based selection of small molecules to alter allele-specific MHC class II antigen presentation.

J. Immunol. 11th ed., 187 , 5921-5930, (2011)

Class II major histocompatibility molecules are the primary susceptibility locus for many autoimmune disorders, including type 1 diabetes. Human DQ8 and I-A(g7), in the NOD mouse model of spontaneous ...
Binding of phosphonate chelating agents and pyrophosphate to apotransferrin.

Biochemistry 30(28) , 6930-6, (1991)

Difference ultraviolet spectroscopy has been used to monitor the binding of a series of phosphonate ligands to human apotransferrin. The ligands consist of pyrophosphate as well as the phosphonic acid...
Synthesis, characterization, and in vitro antitumor activity of osteotropic diam(m)ineplatinum(II) complexes bearing a N,N-bis(phosphonomethyl)glycine ligand.

J. Med. Chem. 46(23) , 4946-51, (2003)

A series of osteotropic (bone-seeking) [(bis(phosphonomethyl)amino-kappaN)acetato-kappaO(2-)]platinum(II) complexes attached to diammine, ethane-1,2-diamine, cis-R,S-cyclohexane-1,2-diamine, trans-S,S...

 Synonyms

Glycine-N,N-bis(methylenephosphonic Acid)
N,N-di(phosphonomethyl) iminoacetic acid
N,N-bis(phosphonomethyl)aminoacetic acid
<<(carboxymethyl)imino>dimethylene>bisphosphonic acid
EINECS 219-468-4
Glyphosine [ANSI]
2-[bis(phosphonomethyl)amino]acetic acid
Glycine,N,N-bis(phosphonomethyl)
Glycine, N,N-bis(phosphonomethyl)-
N,N-bis-(phosphonomethyl)-glycine
Polaris
Glyphosphine
bis-phosphonomethyl glycine
MFCD00056670
2-(Bis(phosphonomethyl)amino)acetic acid
N,N-Bis(phosphonomethyl)glycine
nitriloacetatodimethylenephosphonic acid
N-Carboxymethyl-N,N-bis(methylenephosphonic Acid)amine
Caswell No. 471A
Glyphosine
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